[(η6-p-cymene)RuCl2(1-benzyl-1-azonia-3,5-diaza-7-phosphaadamantyl)]Cl | 1065225-20-8

• 英文名称: [(η6-p-cymene)RuCl2(1-benzyl-1-azonia-3,5-diaza-7-phosphaadamantyl)]Cl
• 英文别名: [(η⁶-p-cymene)RuCl₂(1-benzyl-1-azonia-3,5-diaza-7-phosphaadamantyl)]Cl；[(η⁶-p-cymene)RuCl₂(1,3,5-triaza-7-phosphaadamantane-benzyl)]Cl；[(η⁶-p-cymene)RuCl₂(pta-Bn)]Cl
• CAS: 1065225-20-8
• 化学式: C₂₃H₃₃Cl₂N₃PRu*Cl
• 分子量: 589.938
• InChiKey: USSOMXPWCFQAAY-ZSFFHWGOSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(η6-p-cymene)RuCl2(1-benzyl-1-azonia-3,5-diaza-7-phosphaadamantyl)]Cl 、 sodium 3-(diphenylphosphanyl)benzenesulfonate 以 甲醇 为溶剂， 反应 10.0h， 以76%的产率得到[(η⁶-p-cymene)RuCl₂(1-benzyl-1-azonia-3,5-diaza-7-phosphaadamantyl)](mtppms)
  参考文献：
  名称：

  Two in one: Charged tertiary phosphines held together by ionic or covalent interactions as bidentate phosphorus ligands for synthesis of half-sandwich Ru(II)-complexes

  摘要：

  Ion pairs consisting of N-substituted derivatives of 1,3,5-triaza-7-phosphaadamantane (pta-R; R = benzyl, butyl, hexyl) as cations and monosulfonated triphenylphosphine (mtppms) as anion were synthesized and characterized (including X-ray diffraction, too). These ion pairs act as bidentate phosphorus ligands in reactions with [(eta(6)-C10H14)RuCl2](2), yielding mononuclear or dinuclear half sandwich Ru(II) complexes. Bisphosphine 3 of good water-solubility was synthesized in reaction of pta with 1,4-bis(chloromethyl)benzene and used for the synthesis of the water-soluble dinuclear complex [{(eta(6)-C10H14)RuCl2)(2)(mu-3)]Cl-2. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.05.008
• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 1-benzyl-1-azonia-3,5-diaza-7-phosphaadamantane choride 以 甲醇 为溶剂， 反应 0.33h， 以74%的产率得到[(η6-p-cymene)RuCl2(1-benzyl-1-azonia-3,5-diaza-7-phosphaadamantyl)]Cl
  参考文献：
  名称：

  Two in one: Charged tertiary phosphines held together by ionic or covalent interactions as bidentate phosphorus ligands for synthesis of half-sandwich Ru(II)-complexes

  摘要：

  Ion pairs consisting of N-substituted derivatives of 1,3,5-triaza-7-phosphaadamantane (pta-R; R = benzyl, butyl, hexyl) as cations and monosulfonated triphenylphosphine (mtppms) as anion were synthesized and characterized (including X-ray diffraction, too). These ion pairs act as bidentate phosphorus ligands in reactions with [(eta(6)-C10H14)RuCl2](2), yielding mononuclear or dinuclear half sandwich Ru(II) complexes. Bisphosphine 3 of good water-solubility was synthesized in reaction of pta with 1,4-bis(chloromethyl)benzene and used for the synthesis of the water-soluble dinuclear complex [{(eta(6)-C10H14)RuCl2)(2)(mu-3)]Cl-2. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.05.008