N-trimethylsilylaminoborane trimer | 81132-97-0

• 英文名称: N-trimethylsilylaminoborane trimer
• CAS: 81132-97-0
• 化学式: C₉H₃₆B₃N₃Si₃
• 分子量: 303.094
• InChiKey: BZWLDVUYICXBOY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-trimethylsilyl-μ-aminodiborane(6) 、 六甲基二硅氮烷 以 neat (no solvent) 为溶剂， 以30%的产率得到N-trimethylsilylaminoborane trimer
  参考文献：
  名称：

  Reaction of Hexamethyldisilazane with Borane in Tetrahydrofuran

  摘要：

  AbstractHexamethyldisilazane 1 reacts with borane in tetrahydrofuran (THFBH3, 2) first by formation of an adduct (Me3Si)2NHBH3 (3), and then either to the N,N‐bis‐(trimethylsilyl)‐μ‐aminodiborane 5 or to the mixture of 5 and N‐trimethylsilyl‐μ‐aminodiborane(6) 6, depending on the reaction conditions. The compounds 5 and 6 can be quantitatively converted to the N,N′,N″‐tris(trimethylsilyl)borazine 4. Three intermediates can be identified, namely N,N‐bis(trimethylsilyl)borane 7, N,N‐bis(trimethylsilyl)amino(N′‐trimethylsilylamino)borane 8 and N‐trimethylsilylaminoborane‐trimer. All products and intermediates were characterized by multinuclear NMR spectroscopy, and coupling constant 1J(29Si, 15N) were measured from 29Si NMR spectra by using the Hahn‐echo‐extended (HEED) INEPT pulse sequence.

  DOI：

  10.1002/zaac.19966221208

文献信息

• Nutt, W. R., Dissertation Abstracts International, B: The Sciences and Engineering, Diss. Duke Univ. 1971, S. 1/133, 1971, vol. 32, p. 3240/3241
  作者：Nutt, W. R.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.4, 4.2.4, page 108 - 108
  作者：

  DOI：——

  日期：——
• Reactions of [(organosilyl)amino]boranes with selected hydrides
  作者：W. Rodger Nutt、Richard L. Wells

  DOI：10.1021/ic00136a067

  日期：1982.6
• Collins, A. L., Dissertation Abstracts International, B: The Sciences and Engineering, Diss. Duke Univ. 1966 nach W. R. Nutt (Diss. Duke Univ. 1971, S. 1/133), 1971, vol. 32, p. 3240/3241
  作者：Collins, A. L.

  DOI：——

  日期：——