| 121123-08-8

• CAS: 121123-08-8
• 化学式: C₁₀H₁₀FeO₃
• 分子量: 234.035
• InChiKey: KZUPOKUTQZITKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 trimethoxonium tetrafluoroborate 以 二氯甲烷 为溶剂， 以95%的产率得到(η(5)-cyclopentadienyl)carbonyl[(4-5-η(2))-1-methoxy-2-oxa-4-pentene-1-ylidene]iron(II) tetrafluoroborate
  参考文献：
  名称：

  Chemistry of metallacyclic alkenylcarbene complexes V. Synthesis, structure and SN2′-type reactions of a chelated iron (η2-olefin) dioxocarbene complex

  摘要：

  The novel ferracyclic (eta(2)-alkene)carbene complexes of type 3 and 9 are easily accessible either from the corresponding (omega-alkenyl)carbene complexes 1 or from the chelated (eta(2)-olefin)acyl complex 8, depending on the central metal fragment and the heteroatom substituent X at the carbene carbon atom. X-ray structural data of 9 are provided and compared with those of 3 and similar metallacycles of the 'earlier' transition metals W and Mn. With nucleophiles, 9 yields new (eta(2)-olefin) complexes bearing a substituted rearranged alkene ligand in an S(N)2'-type reaction, thus offering a new method for the a-allylation of carbon nucleophiles like enoxyborates.

  DOI：

  10.1016/s0022-328x(96)06545-x