fac-[Mn(CN-t-Bu)(CO)3((Ph2P)2CC(CN)C6H4CH(CN)2)]BF4 | 1034909-75-5

• 英文名称: fac-[Mn(CN-t-Bu)(CO)3((Ph2P)2CC(CN)C6H4CH(CN)2)]BF4
• CAS: 1034909-75-5
• 化学式: BF₄*C₄₄H₃₄MnN₄O₃P₂
• 分子量: 870.469
• InChiKey: IVVVZIMSCSCTTD-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  fac-[Mn(CN-t-Bu)(CO)3((Ph2P)2CC(CN)C6H4CH(CN)2)]BF4 在 KOH 作用下， 以 二氯甲烷 为溶剂， 生成 fac-Mn(CN-t-Bu)(CO)3((Ph2P)2CC(CN)C6H4C(CN)2)
  参考文献：
  名称：

  D⁺−π−A⁻ Charge-Transfer Molecules Based on Tricyanoquinodimethane and Diphosphine Metal Complexes

  摘要：

  A new family of D+-pi-A(-) chromophores in which the donor group is an organometallic complex and the acceptor group a tricyanoquinodimethane moiety has been synthesized by the reaction of diphosphinomethanide transition-metal complexes and 7,7',8,8'-tetracyanoquinodimethane.

  DOI：

  10.1021/ic8008333
• 作为产物：
  描述：

  tetrafluoroboric acid 、 fac-Mn(CN-t-Bu)(CO)3((Ph2P)2CC(CN)C6H4C(CN)2) 以 二氯甲烷 为溶剂， 生成 fac-[Mn(CN-t-Bu)(CO)3((Ph2P)2CC(CN)C6H4CH(CN)2)]BF4
  参考文献：
  名称：

  D⁺−π−A⁻ Charge-Transfer Molecules Based on Tricyanoquinodimethane and Diphosphine Metal Complexes

  摘要：

  A new family of D+-pi-A(-) chromophores in which the donor group is an organometallic complex and the acceptor group a tricyanoquinodimethane moiety has been synthesized by the reaction of diphosphinomethanide transition-metal complexes and 7,7',8,8'-tetracyanoquinodimethane.

  DOI：

  10.1021/ic8008333