(mer-(2,6-bis(pyrazol-1-ylmethyl)pyridine)Ni(H2O)2Cl)Cl*H2O | 1312936-68-7

• 英文名称: (mer-(2,6-bis(pyrazol-1-ylmethyl)pyridine)Ni(H2O)2Cl)Cl*H2O
• CAS: 1312936-68-7
• 化学式: C₁₃H₁₇ClN₅NiO₂*Cl*H₂O
• 分子量: 422.922
• InChiKey: MKSXQRJAYXCVQU-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 2,6-bis((1H-pyrazol-1-yl)methyl)pyridine 以 甲醇 、 乙腈 为溶剂， 以60%的产率得到(mer-(2,6-bis(pyrazol-1-ylmethyl)pyridine)Ni(H2O)2Cl)Cl*H2O
  参考文献：
  名称：

  Conformational flexibility of 2,6-bis(pyrazol-1-ylmethyl)pyridine (L5) in [(L5)CoII(H2O)3]Cl2 and [(L5)NiII(H2O)2Cl]Cl·H2O. Molecular structures and non-covalent interactions

  摘要：

  Using a non-planar tridentate ligand 2,6-bis(pyrazol-1-ylmethyl) pyridine (L-5) two new coordination complexes [(L-5)Co-II(H2O)(3)]Cl-2 (1) and [(L-5)Ni-II(H2O)(2)Cl]Cl center dot H2O (2) have been synthesized and structurally characterized. Complex 1 has N3O3 distorted octahedral environment around Co-II with coordination by L-5 (two pyrazole and a pyridine nitrogen in a facial mode) and three water molecules. Complex 2 has N3O2Cl distorted octahedral geometry around Ni-II with meridional L-5 coordination, two water molecules, and a Cl ion. Analysis of the crystal packing diagram reveals the involvement of solvent (water as metal-coordinated and as solvent of crystallization) and counteranion (Cl ) to play significant roles in generating 1D chains, involving O-H center dot center dot center dot Cl, and O-H center dot center dot center dot O interactions. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.038