tetrakis(di-p-tolylantimony)di-μ4-peroxo-tetroxide | 445401-75-2

• 英文名称: tetrakis(di-p-tolylantimony)di-μ4-peroxo-tetroxide
• CAS: 445401-75-2
• 化学式: C₅₆H₅₆O₈Sb₄
• 分子量: 1344.06
• InChiKey: HZNAHZUWGOHZPS-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  tetrakis(di-p-tolylantimony)hexoxide 、 双氧水 以 乙醚 、 水 为溶剂， 以92.4%的产率得到tetrakis(di-p-tolylantimony)di-μ4-peroxo-tetroxide
  参考文献：
  名称：

  Oxidation of tetraaryldistibanes: syntheses and crystal structures of diarylantimony oxides and peroxides, (R2Sb)2O, (R2Sb)4O6 and (R2SbO)4(O2)2 (R=Ph, o-Tol, p-Tol)

  摘要：

  Tetraaryldistibanes, (R2Sb)(2) (R = Ph, o-Tol, p-Tol) are synthesized by the reactions of R2SbNa with BrCH2CH2Br in liquid ammonia. They react with air oxygen to form (R2Sb)(4)O-6 and (R2Sb)(4)O-6. The reactions of (R2Sb)(4)O-6 with H2O2 give peroxides, (R2SbO)(4)(O-2)(2), Single-crystal X-ray structure analyses reveal that the conformations of the (R2Sb)(2)O-6 molecules are close to syn-syn (R = Ph) or to syn-anti (R = o-Tol, p-Tol). (Ph2SbO)(4)(O-2)(2) is an antimony-oxygen cluster with mu(4)-peroxo ligands. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01466-8