[5-PPh3-7-Me-μ-(9,10-HMeC)-nido-7-CB10H9] | 725734-66-7

• 英文名称: [5-PPh3-7-Me-μ-(9,10-HMeC)-nido-7-CB10H9]
• CAS: 725734-66-7
• 化学式: C₂₂H₃₁B₁₀P
• 分子量: 434.572
• InChiKey: WIIAZUGNLZYNDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [5-PPh3-7-Me-μ-(9,10-HMeC)-nido-7-CB10H9] 以 氘代甲苯 为溶剂， 生成 [6-PPh3-7-Me-μ-(9,10-HMeC)-nido-7-CB10H9]
  参考文献：
  名称：

  New Derivatives of [NHMe₃][7-Me-μ-(9,10-HMeC)-nido-7-CB₁₀H₁₀]

  摘要：

  [NHMe3][7-Me-mu-(9, 10-HMeC)-nido-7-CB10H10] (1) reacts with [PdCl2(PPh3)(2)] in refluxing ethanol solutions to afford four compounds which are the result of PPh3 addition. Three of the products are structural isomers, viz. [5-PPh3-7-Me-mu-(9,10-HMeC)-nido-7-CB10Hg9] (2), [6-PPh3-7-Me-mu-(9,10-HMeC)-nido-7-CB10H9] (3), and [2-Me-3-{CHMe(PPh3)}-closo-2-CB10H9] (4), and the fourth is [7-Me-8-OEt-9-fCHMe(PPh3)}-nido-7-CB10H10] (5). The compounds were characterized by NMR spectrometry, high-resolution mass spectrometry, and single-crystal X-ray diffraction studies and are the first derivatives of the "unreactive" [7-R-mu-(9,10-HRC)-nido-7-CB10H10](-) anion (R = Me) not involving degradation.

  DOI：

  10.1021/om030487v
• 作为产物：
  描述：

  [NHMe3][7-Me-μ-(9,10-HMeC)-nido-7-CB10H10] 、 bis-triphenylphosphine-palladium(II) chloride 以 乙醇 为溶剂， 以10%的产率得到[5-PPh3-7-Me-μ-(9,10-HMeC)-nido-7-CB10H9]
  参考文献：
  名称：

  New Derivatives of [NHMe₃][7-Me-μ-(9,10-HMeC)-nido-7-CB₁₀H₁₀]

  摘要：

  [NHMe3][7-Me-mu-(9, 10-HMeC)-nido-7-CB10H10] (1) reacts with [PdCl2(PPh3)(2)] in refluxing ethanol solutions to afford four compounds which are the result of PPh3 addition. Three of the products are structural isomers, viz. [5-PPh3-7-Me-mu-(9,10-HMeC)-nido-7-CB10Hg9] (2), [6-PPh3-7-Me-mu-(9,10-HMeC)-nido-7-CB10H9] (3), and [2-Me-3-{CHMe(PPh3)}-closo-2-CB10H9] (4), and the fourth is [7-Me-8-OEt-9-fCHMe(PPh3)}-nido-7-CB10H10] (5). The compounds were characterized by NMR spectrometry, high-resolution mass spectrometry, and single-crystal X-ray diffraction studies and are the first derivatives of the "unreactive" [7-R-mu-(9,10-HRC)-nido-7-CB10H10](-) anion (R = Me) not involving degradation.

  DOI：

  10.1021/om030487v