| 1211421-32-7

• CAS: 1211421-32-7
• 化学式: C₂₄H₁₉CuN₄O₂*F₆P
• 分子量: 603.951
• InChiKey: FINFASCWWVXARJ-YOMCRPSHSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetrakis(actonitrile)copper(I) hexafluorophosphate 、 2-[(2-pyridinylmethylene)amino]phenol 在 air 作用下， 以 乙腈 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Grid-corner analogues: Synthesis, characterisation and spectroscopic properties of meridional complexes of tridentate NNO Schiff-base ligands

  摘要：

  Reactions of the tridentate Schiff-base ligands HL1, HL2 and HL3 formed from pyridine-2-aldehyde and 2-aminophenol plus two of its methoxycarbonyl derivatives, with AgNO3, [Cu(CH3CN)(4)]PF6, Cu(NO3)(2), Co(NO3)(2) and Zn(NO3)(2) give complexes of the following types: [Ag(HL)(2)]NO3 (1a, 2a, 3a); [Cu-II(HL)L]PF6 (1b, 2b, 3b): [Cu-II(HL)L]NO3 (1c, 2c, 3c); and [M(HL)L](2)[M(NO3)(4)] where M=Co(II) (1d, 2d, 3d): or Zn(II) (1e, 2e, 3e), which in principle define the basic characteristics of the metal sites in certain metallogrids. The complexes have been characterized by spectroscopic techniques and elemental analysis. The solid state structures of complexes 2b and 2e have been established by X-ray crystallography. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.06.069