[Al(2,2'-thiobis(6-tert-butyl-4-methylphenol-2H)(CH3)(Et2O)] | 851297-09-1

• 英文名称: [Al(2,2'-thiobis(6-tert-butyl-4-methylphenol-2H)(CH3)(Et2O)]
• CAS: 851297-09-1
• 化学式: C₂₇H₄₁AlO₃S
• 分子量: 472.668
• InChiKey: SALYPWRCPZOVSL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  乙醚 、 [Al(2,2'-thiobis(6-tert-butyl-4-methylphenolato)Me]2 以 乙醚 为溶剂， 以79%的产率得到[Al(2,2'-thiobis(6-tert-butyl-4-methylphenol-2H)(CH3)(Et2O)]
  参考文献：
  名称：

  Aluminum Complexes with Sulfide-Linked Bis(phenolato) Ligands:  Unusual Structure and Reactivity of the Methyl Bis(phenolato) Complex “[Al(tbmp)Me]” (tbmp = 2,2‘-Thiobis(6-tert-butyl-4-methylphenolato))

  摘要：

  Trialkylaluminum complexes, AIR(3) (R = Me, Et), reacted with the sulfide-bridged his(phenol) tbmpH(2) (tbmpH(2) = 2,2'-thiobis(6-tert-butyl-4-methylphenol)) in a 1:1 ratio to give monoalkyl compounds of the composition "[Al(tbmp)R]" with an unsymmetrical dinuclear structure with both six- and four-coordinate aluminum centers in the solid state. The reaction of 2 equiv of tbmpH(2) gave [Al(tbmp)(tbmpH)], which could be deprotonated with triethylamine to give [NEt3H] [Al(tbmp)(2)]. Upon reaction of [Al(tbmp)R](2) with Lewis bases L (L = Et2O, THF, propylene oxide), monomeric, five-coordinate adducts [Al(tbmp)R(L)] were formed, while 2-propanol gave the dinuclear complex [Al(tbmp)(mu-(OPr)-Pr-i)](2).

  DOI：

  10.1021/om049067b