[Zn(II)Cl2(4,4'-bis(dibutylaminostyryl)-[2,2']-bipyridine)] | 258328-50-6

• 英文名称: [Zn(II)Cl2(4,4'-bis(dibutylaminostyryl)-[2,2']-bipyridine)]
• 英文别名: [ZnCl2(4,4'-bis(para-di-n-butylaminostyryl)-2,2'-bipyridine)]；[ZnCl2(NBu2bipy)
• CAS: 258328-50-6
• 化学式: C₄₂H₅₄Cl₂N₄Zn
• 分子量: 751.214
• InChiKey: VMPLUBRSODVNMB-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  zinc(II) chloride dihydrate 、 4,4′-(para-di-n-butylaminostyryl)-2,2′-bipyridine 以 二氯甲烷 为溶剂， 生成 [Zn(II)Cl2(4,4'-bis(dibutylaminostyryl)-[2,2']-bipyridine)]
  参考文献：
  名称：

  Zinc(II) as a Versatile Template for the Design of Dipolar and Octupolar NLO-phores

  摘要：

  Thermally stable dipolar and octupolar (D2d, D3) NLO-phores are readily accessible by combining one, two, or three 4,4'-bis(dialkylaminostyryl)-[2,2']-bipyridyl ligands with zinc(II) salts. The off-resonant beta0 values point out the superiority of octupoles versus dipoles in terms of nonlinearity/transparency tradeoff. The octahedral tris(bipyridyl)zinc(II) complex exhibits a very large beta0 value (241 x 10-30 esu), which is the largest ever reported for octupolar molecules.

  DOI：

  10.1021/ja025705a