[(μ-η2:η2-HCC)Rh2(CO)2(3,5-bis(diphenylphosphino)methyl)pyrazolato)] | 663600-90-6

• 英文名称: [(μ-η2:η2-HCC)Rh2(CO)2(3,5-bis(diphenylphosphino)methyl)pyrazolato)]
• CAS: 663600-90-6
• 化学式: C₃₃H₂₆N₂O₂P₂Rh₂
• 分子量: 750.34
• InChiKey: PVFDQOFUFUFPEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [(CO)2Rh(3,5-bis((diphenylphosphino)methyl)pyrazolato)Rh(CO)2]BF4 、 乙炔氢锂 以 not given 为溶剂， 生成 [(μ-η2:η2-HCC)Rh2(CO)2(3,5-bis(diphenylphosphino)methyl)pyrazolato)]
  参考文献：
  名称：

  Tetranuclear Complexes Based on a Dynamic Metal−Metal Linkage, [(μ₄-X)Rh₄(CO)₄(PNNP)₂]ⁿ⁺ (X/n = RC⋮C/1 (Acetylide), C₂/0 (Dicarbide))

  摘要：

  Tetrarhodium complexes with a PNNP auxiliary, [(mu(4)-X)Rh-4(CO)(4)(PNNP)(2)](n+) (X/n = RCequivalent toC/1 (acetylide), C-2/0 (dicarbide); PNNP = 3,5-bis((diphenylphosphino)methyl)pyrazolato), are integrated mainly through M-X interactions and exhibit unique dynamic behavior associated with reversible metal-metal bond cleavage and recombination processes.

  DOI：

  10.1021/om034315+