RuCl2(anthcin)(triphenylarsine)2 | 440106-76-3

• 英文名称: RuCl2(anthcin)(triphenylarsine)2
• CAS: 440106-76-3
• 化学式: C₅₂H₄₂As₂Cl₂NO₂Ru
• 分子量: 1034.73
• InChiKey: PCMVYAIWZNRZOU-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  trichlorotris(triphenylarsine)ruthenium(III) 、 anthranilic acid cinnamaldehyde 以 苯 为溶剂， 以80%的产率得到RuCl2(anthcin)(triphenylarsine)2
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERISATION OF RUTHENIUM(III) COMPLEXES CONTAINING MONOBASIC BIDENTATE SCHIFF BASES AND THEIR BIOLOGICAL ACTIVITIES

  摘要：

  New hexa-coordinated ruthenium(III) complexes of the type [RuX2(L)(EPh3)(2)] (X=Cl or Br; L=monobasic bidentate Schiff base ligand; E = P or As) have been synthesised by the reactions of [RuCl3(PPh3)(3)], [RuCl3(AsPh3)(3)], [RuBr3(AsPh3)(3)] or [RuBr3(PPh3)(2)(MeOH)] with the appropriate ligands such as anthranilic acid cinnamaldehyde (Hanthcin), anthranilic acid p-tolualdehyde (Hanth-p-tol) and anthranilic acid p-anisaldehyde (Hanth-p-ans). All of these new complexes were characterised using various physico-chemical methods such as elemental analyses, spectral (IR, electronic and EPR), magnetic moment and cyclic voltammetric data. The antibacterial activities of ligands and their complexes have also been determined. An octahedral structure has been tentatively assigned to all of the new complexes.

  DOI：

  10.1081/sim-120003211