(2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)(cyclopentadienyl)iron(II) | 1300707-59-8

• 英文名称: (2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)(cyclopentadienyl)iron(II)
• CAS: 1300707-59-8
• 化学式: C₃₄H₄₆FeN₂
• 分子量: 538.6
• InChiKey: GTEFMFKJLRGKJQ-GGFZQTNZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  4-叔丁基吡啶 、 (2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)(cyclopentadienyl)iron(II) 以 氘代苯 为溶剂， 生成 (2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)(cyclopentadienyl)(4-tert-butylpyridine)iron(II)
  参考文献：
  名称：

  C–H activation by a terminal imidoiron(III) complex to form a cyclopentadienyliron(II) product

  摘要：

  Imido complexes of the late transition metals have the ability to activate C-H bonds through the abstraction of hydrogen atoms from hydrocarbons. This paper describes the apparent hydrogen atom transfer from cyclopentadiene (CpH) to the isolable imidoiron(III) complex L(Me)FeNAd (L(Me) = 2,4-bis(2,6-diisopropylphenylimido)pent-3-yl; Ad = 1-adamantyl) in the presence of 4-tert-butylpyridine ((t)Bupy). The isolated product is not the amidoiron(II) complex, but instead it is L(Me)Fe(Cp)((t)Bupy), the result of amido protonation by additional CpH. The crystal structures of both L(Me)FeCp and L(Me)Fe(Cp)((t)Bupy) are presented, and in the latter compound the Fe-C bonds are longer than in any previously characterized cyclopentadienyliron complex. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.11.031
• 作为产物：
  描述：

  (2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)(cyclopentadienyl)(4-tert-butylpyridine)iron(II) 以 氘代苯 为溶剂， 生成 (2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)(cyclopentadienyl)iron(II)
  参考文献：
  名称：

  C–H activation by a terminal imidoiron(III) complex to form a cyclopentadienyliron(II) product

  摘要：

  Imido complexes of the late transition metals have the ability to activate C-H bonds through the abstraction of hydrogen atoms from hydrocarbons. This paper describes the apparent hydrogen atom transfer from cyclopentadiene (CpH) to the isolable imidoiron(III) complex L(Me)FeNAd (L(Me) = 2,4-bis(2,6-diisopropylphenylimido)pent-3-yl; Ad = 1-adamantyl) in the presence of 4-tert-butylpyridine ((t)Bupy). The isolated product is not the amidoiron(II) complex, but instead it is L(Me)Fe(Cp)((t)Bupy), the result of amido protonation by additional CpH. The crystal structures of both L(Me)FeCp and L(Me)Fe(Cp)((t)Bupy) are presented, and in the latter compound the Fe-C bonds are longer than in any previously characterized cyclopentadienyliron complex. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.11.031