| 202918-27-2

• CAS: 202918-27-2
• 化学式: C₄₁H₃₆ClN₂P₃Ru
• 分子量: 786.195
• InChiKey: SPKJSWGXPQTGIV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二(三苯基膦)环戊二烯基氯化钌(II) 、 N,N-双(二苯磷)胺 以 甲苯 为溶剂， 以47%的产率得到[RuCl(Cp)(η(2)-bis(diphenylphosphino)amine)]
  参考文献：
  名称：

  Substitution reactions of CpRu(PPh3)2Cl with PPh2H and dppa

  摘要：

  One PPh3 group of CpRu(PPh3)(2)Cl is easily substituted by PPh2H to give the asymmetrical complex CpRu(PPh3)(PPh2H)Cl (1) in a very good yield. Attempts to form the lambda(4)-phosphanediyl complex CpRu(PPh3)=PPh2 (1') by selective dehydrohalogenation of 1 failed. However, by using one equivalent of the chelating diphosphine dppa two PPh3 ligands are substituted to yield CpRu(dppa)Cl (2). With an excess of dppa the reaction yielded the N-iminophosphoranyl-substituted dppa complex CpRu{(PPh2)(2)NPPh2=NH}Cl (3) and PPh2H. H-1, C-13{H-1} and P-31{H-1} NMR, IR and mass spectra of 1-3 are given. Crystals of 1 are monoclinic, space group P2(1)/c with a = 11.8446(12), b = 14.502(3), c = 17.504(2) Angstrom and beta = 95.55(9)degrees, Z = 4 and R = 0.0270 for 4299 observed reflections. Crystals of 2 are monoclinic, space group P2(1)/c with a = 10.7616(14), b = 18.263(4), c = 13.859(2) Angstrom and beta = 110.41(1)degrees, Z = 4 and R = 0.0327 for 4227 observed reflections. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05785-x