bis(1,4-di-tert-butylbenzene)chromium(1+) | 254112-71-5

• 英文名称: bis(1,4-di-tert-butylbenzene)chromium(1+)
• CAS: 254112-71-5
• 化学式: C₂₈H₄₄Cr
• 分子量: 432.653
• InChiKey: HUUBQRBAVHCPNL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(η6-1,4-di-tret-butylbenzene)chromium 以 二氯甲烷 为溶剂， 生成 bis(1,4-di-tert-butylbenzene)chromium(1+)
  参考文献：
  名称：

  Synthesis, structure and spectroelectrochemistry of bis(η6-1,4-tri-tert-butyl-benzene)chromium(0) and bis(η5-1,2,4-tri-tert-butyl-cyclopentadienyl)cobalt(II). Dia- and paramagnetic sandwich complexes derived from sterically highly demanding π-ligands

  摘要：

  Metal atom synthesis gives access to the bis(arene)chromium sandwich of 1,4 di-tert-butyl-benzene (5). 5 displays an axial sandwich structure with a linear arene-chromium-arene axis and a Cr-arene distance of 1.64 Angstrom. Reduction of [{(eta(5)-1,2,4 tri-tert-butyl-Cp)CoCl}(2)] with the trianion of decacyclene in THF produces the cobaltocene sandwich [(eta(5)-1,2,4 tri-tert-butyl Cp)(2)Co] 2 as black crystals in 65% yield. Electrochemistry shows that the monocations 2(+) and 5(+) are able to support reversibly the one-electron reduction to their corresponding neutral congeners. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00383-6