Mo(CO)4(η2-PPh2(o-C6H4)CH=NMe) | 306972-41-8

• 英文名称: Mo(CO)4(η2-PPh2(o-C6H4)CH=NMe)
• CAS: 306972-41-8
• 化学式: C₂₄H₁₈MoNO₄P
• 分子量: 511.325
• InChiKey: ABSXGPXPHYPLJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Mo(CO)3(1,3,5-trimethyl-1,3,5-triazacyclohexane) 、 2-二苯基膦苯甲醛 以 二氯甲烷 为溶剂， 以30%的产率得到Mo(CO)2(η3-PCHO)2
  参考文献：
  名称：

  Synthesis of Mo(CO)2(η3-PPh2(o-C6H4)C(O)H)2 and its reaction with C60

  摘要：

  Reaction of Mo(CO)(3)(NCMe)(3) and PPh2(o-C6H4)C(=O)H (abbreviated as PCHO) at room temperature affords Mo(CO)(2)(eta(3)-PCHO)(2) (1), while compound 1 and the phosphine-imine complex Mo(CO)(4)(eta(2)-PPh2(o-C6H4)CH=NMe) (2) are obtained by using Mo(CO)(3)(eta(3)-(MeNCH2)(3)) as the reactant. Thermal reaction of 1 with C-60 products Mo(CO)(2)(eta(4)-(PPh2(o-C6H4)CH)(2))(eta(2)-C-60) (3) in low yield, apparently through coupling of the formyl moieties. The structures of 1 and 3 have been determined by an X-ray diffraction study. The two aldehyde groups of 1 and C-60 ligand of 3 are coordinated to the molybdenum atom in a pi-fashion. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.01.023