[CoCl2(N,N'-Te2(NtBu)4)] | 1217311-52-8

• 英文名称: [CoCl2(N,N'-Te2(NtBu)4)]
• CAS: 1217311-52-8
• 化学式: C₁₆H₃₆Cl₂CoN₄Te₂
• 分子量: 669.588
• InChiKey: XGSVGVLJJVEOKA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(t-butyl)NTe(μ-N(t-butyl))2TeN(t-butyl)] 、 cobalt(II) chloride 以 甲苯 为溶剂， 以85%的产率得到[CoCl2(N,N'-Te2(NtBu)4)]
  参考文献：
  名称：

  Cobalt complexes of a selenium diimide and a tellurium diimide dimer

  摘要：

  [CoCl(2){N,N'-Te(2)(N(t)Bu)(4)}] (1) was obtained in good yields by the reaction of equimolar amounts of ((t)Bu)N-Te(mu-N(t)Bu)(2)TeN((t)Bu) and CoCl(2) in toluene under an argon atmosphere. The crystal structure of 1 center dot CH(2)Cl(2) showed that the dimeric tellurium diimide ligand is N,N'-chelated to cobalt. The related reaction of Se(N(t)Bu)(2) and CoCl(2) affords a green product tentatively identified as a 1:1 adduct [CoCl(2){N,N'-Se(N(t)Bu)(2)}] (CHN analysis). However, recrystallization from thf produces the ion-separated complex [Co(2)(mu-Cl)(3){N,N'-Se(N(t)Bu)(2)}(2)(thf)(2)][CoCl(3){NH(2)((t)Bu)}]center dot 11/2thf (2.11/2thf), in which the monomeric selenium diimide ligand is N,N'-chelated to cobalt in the cation. A pathway for the formation of 2 from [CoCl(2){N,N'-Se(NtBu)(2)}] in thf is proposed. (c) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.10.006