1,6-diphenylamino-10-chloro-5-phenyl-2-methyl-1,3,2-diazapalladolo[1,2-b],1,2,3-benzodiazapalladol | 494205-55-9

• 英文名称: 1,6-diphenylamino-10-chloro-5-phenyl-2-methyl-1,3,2-diazapalladolo[1,2-b],1,2,3-benzodiazapalladol
• CAS: 494205-55-9
• 化学式: C₂₇H₂₃ClN₄Pd
• 分子量: 545.379
• InChiKey: MIQOHNIKMQEPTP-SMCHWGACSA-M

反应信息

• 作为产物：
  描述：

  bis(N,N-diphenylhydrazone) of methylglyoxal 、 palladium dichloride 以 neat (no solvent) 为溶剂， 以65%的产率得到1,6-diphenylamino-10-chloro-5-phenyl-2-methyl-1,3,2-diazapalladolo[1,2-b],1,2,3-benzodiazapalladol
  参考文献：
  名称：

  Cyclopalladated Complexes Derived from Diphenylhydrazones and their Transmetallation Reaction

  摘要：

  Mononuclear cyclopalladated complexes of type PdCl(Ph2N-N=CR1-C-R-2=N-NPh2), where R-1=R-2=H (2a), R-1= R-2=CH3 (2b), and R-1=H, R-2=CH3 (2c) were synthesized by the reaction of palladium chloride and hydrazones. Additionally, the reaction of the complex 2c towards lithium phenylacetylide was studied, giving Ph2N-N = C(CH3)-CH = N-N(Ph)(o-C6H4- -C-C-Ph) (3). The complexes 2a-2c and compound 3 were characterized by IR, Mass, H-1, C-13, and 2D NMR spectroscopy. X-ray structure of complex 2c was also determined.

  DOI：

  10.1002/1521-3749(200209)628:9/10<2104::aid-zaac2104>3.0.co;2-a