(1,4,7,10-tetraazacyclododeca-5,6,11,12-tetraaminopiperizine-4,6,10,12-tetraene)MnCl2 | 464932-86-3

• 英文名称: (1,4,7,10-tetraazacyclododeca-5,6,11,12-tetraaminopiperizine-4,6,10,12-tetraene)MnCl2
• CAS: 464932-86-3
• 化学式: C₂₄H₄₄Cl₂MnN₁₂
• 分子量: 626.538
• InChiKey: IWWDBRCEQIMUDR-ZQBUCXJESA-L

反应信息

• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 1,4,7,10-tetraazacyclododeca-5,6,11,12-tetraaminopiperizine-4,6,10,12-tetraene 在 CH₃COOH/CH₃COONa buffer (pH 4) 作用下， 以 甲醇 、 水 为溶剂， 以54%的产率得到(1,4,7,10-tetraazacyclododeca-5,6,11,12-tetraaminopiperizine-4,6,10,12-tetraene)MnCl2
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF NOVEL MACROCYCLES AND THEIR COMPLEXES WITH TRANSITION METAL IONS

  摘要：

  Novel Schiff base macrocycles, 1,4,7,10-tetraazacyclododeca-5,6,11,12-tetraaminoisobutyric acid-4,6,10,12-tetraene (L-1), 1,4,7,10-tetraazacyclododeca-5,6,11,12-tetraaminopiperizine-4,6,10,12-tetraene (L-2) and 1,4,7,10-tetraazacyclodeca-5,6,11,12-tetraaminouracil-4,6,10,12-tetraene (L-3) containing pendant groups have been synthesized by reactions of oxamidediisobutyric acid, oxamidedipiperizine or oxamidediuracil, respectively, with ethylenediamine. Their first-row transition metal complexes of the types [M(L)Cl-2] and [M(L)Cl-2]Cl have been prepared. All of the compounds have been characterized on the basis of elemental analyses, IR, UV-Visible, EPR, NMR spectroscopy, magnetic moments and conductance measurements. The complex of divalent metal ions are non-ionic while those of trivalent metal ions are 1:1 electrolytes. For all of these complexes an octahedral stereochemistry has been proposed.

  DOI：

  10.1081/sim-120005614