CoCl2(4,2'-6',4''-terpyridine) | 210772-44-4

• 英文名称: CoCl2(4,2'-6',4''-terpyridine)
• CAS: 210772-44-4
• 化学式: C₁₅H₁₁Cl₂CoN₃
• 分子量: 363.172
• InChiKey: GKPPZXUNYCKRPU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4,2':6',4''-三联吡啶 、 cobalt(II) chloride 以 乙醇 、 水 为溶剂， 以66.6%的产率得到CoCl2(4,2'-6',4''-terpyridine)
  参考文献：
  名称：

  Coordination compounds of 4,2′-6′,4″-terpyridine, [MCl2(4,2′-6′,4″-terpyridine)], M = Mn(II), Co(II), Ni(II), Cu(II) or Zn(II). Crystal structure of catena-poly [(dichlorozinc)-μ-(4,2′-6′,4″-terpyridine)]

  摘要：

  MCl2 (4,2'-6',4 "-terpyridine) compounds, where M = Mn(II), Co(II), Ni(II),Cu(II) or Zn(II), have been synthesized and characterized by IR and electronic spectroscopy and susceptibility magnetic measurements. Crystalline structure of the Zn(II) complex has been determined by;X-ray diffraction. The Zn(II) atom shows to be in a highly distorted tetrahedral environment, defined by two Cl atoms and two N atoms of two ligand molecules, that act as bridges bound through the N atoms of the external pyridine rings. The structure is made of chains that do not interact among-them. (C) 1998 Elsevier Science ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00420-8