| 492447-68-4

• CAS: 492447-68-4
• 化学式: C₁₉H₂₀CoNO₆S₃
• 分子量: 513.562
• InChiKey: NSOGWWAVSRTKJN-LWFKIUJUSA-L

反应信息

• 作为产物：
  描述：

  、 在 PPh₃ 作用下， 以 苯 为溶剂， 以48%的产率得到
  参考文献：
  名称：

  Novel Phosphine- and Phosphite-Induced Imido Migration to a Cyclopentadienyl Ring in an Imido-Bridged Cobaltadithiolene Complex

  摘要：

  The mechanism of phosphine- and phosphite-induced migration of the imido group from sulfur to a Cp ring in a tosylimido-bridged cobaltadithiolene complex was investigated, and a probable intermediate was isolated and characterized. The presence of a large excess of PPh3 causes the formation of the imido- and phosphine-substituted Cp complex.

  DOI：

  10.1021/om0207212