[(Ru(P(OCH3)3)2)2(.mu-SCH2CH=CHCH2CH3S)(μ-Cl)2(μ-m-xylylenedicyanide)](CF3SO3) | 936500-76-4

• 英文名称: [(Ru(P(OCH3)3)2)2(.mu-SCH2CH=CHCH2CH3S)(μ-Cl)2(μ-m-xylylenedicyanide)](CF3SO3)
• CAS: 936500-76-4
• 化学式: CF₃O₃S*C₂₇H₅₃Cl₂N₂O₁₂P₄Ru₂S₂
• 分子量: 1207.87
• InChiKey: RQPHHOMDAYBVQM-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 戊烯 、 [(Ru(P(OCH3)3)2)2(.mu-S2)(μ-Cl)2(μ-m-xylylenedicyanide)](CF3SO3)2 以 甲醇 为溶剂， 生成 [(Ru(P(OCH3)3)2)2(.mu-S2)(μ-Cl)2(μ-m-xylylenedicyanide)](CF3SO3) 、 [(Ru(P(OCH3)3)2)2(.mu-SCH2CH=CHCH2CH3S)(μ-Cl)2(μ-m-xylylenedicyanide)](CF3SO3) 、 [(Ru(P(OCH3)3)2)2(.mu-SCH2CH=CHCH2CH3SCH3)(μ-Cl)2(μ-m-xylylenedicyanide)](CF3SO3)2
  参考文献：
  名称：

  C−H Cleavage and Double Alkyl Additions to the Disulfido Ligand in Dicyanido-Bridged Ru₂S₂ Complexes

  摘要：

  Novel dicyanido-bridged dicationic (RuSSRuIII)-S-III complexes [{Ru(P(OCH3)(3))(2)}(2)(mu-S-2)(mu-X)(2){mu-m-C6H4(CH2CN)(2)}](CF3SO3)(2) (4, X = Cl, Br) were synthesized by the abstraction of the two terminal halide ions of [{RuX(P(OCH3)(3))(2)}(2)(mu-S-2)(mu-X)(2)] (1, X = Cl, Br) followed by treatment with m-xylylenedicyanide. 4 reacted with 2,3-dimethylbutadiene to give the C4S2 ring-bridged complex [{Ru(P(OCH3)(3))(2)}(2){mu-SCH2C(CH3)C(CH3)CH2S}(mu-X)(2){mu-m-C6H4(CH2CN)(2)}](CF3SO3)(2) (6, X = Cl, Br). In addition, 4 reacted with 1-alkenes in CH3OH to give alkenyl disulfide complexes [{Ru(P(OCH3)(3))(2)}(2){mu-SS(CH2CCHR)}(mu-Cl)(2){mu-m-C6H4(CH2CN)(2)}](CF3SO3) (7: R = CH2CH3, 9: R = CH2CH2CH3) and alkenyl methyl disulfide complexes [{Ru(P(OCH3)(3))(2)}(2){mu-S(CH3)S(CH2CHR)}(mu-Cl)(2){mu-m-C6H4(CH2CN)(2)}](CF3SO3)(2) (8: R = CH2CH3, 10: R = CH2CH2CH3) via the activation of an allylic C-H bond followed by the elimination of H+ or condensation with CH3OH. Additionally, the reaction of 4 with 3-penten-1-ol gave [{Ru(P(OCH3)(3))(2)}(2){mu-SS(CH2CCHCH2OH)}(mu-Cl)(2){mu-m-C6H4(CH2CN)(2)}](CF3SO3) (11) via the elimination of H+ and [{Ru(P(OCH3)(3))(2)}(2)(mu-SCH2CHCHCH2S)(mu-Cl)(2){mu-m-C6H4(CH2CN)(2)}](CF3SO3)(2) (12) via the intramolecular elimination of a H2O molecule. 12 was exclusively obtained from the reaction of 4 with 4-bromo-1-butene.

  DOI：

  10.1021/ic062460k