CuBr(2-(diphenylphosphano)benzaldehyde)2 | 1007838-79-0

• 英文名称: CuBr(2-(diphenylphosphano)benzaldehyde)2
• 英文别名: CuBr(PCHO)2
• CAS: 1007838-79-0
• 化学式: C₃₈H₃₀BrCuO₂P₂
• 分子量: 724.053
• InChiKey: MMSULWKYBVEALU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-二苯基膦苯甲醛 、 copper(I) bromide 以 乙腈 为溶剂， 以24%的产率得到CuBr(2-(diphenylphosphano)benzaldehyde)2
  参考文献：
  名称：

  Three- and four-coordinate copper(I) halide complexes of 2-(diphenylphosphano)benzaldehyde: Dimerization induced by thione-S ligation

  摘要：

  Reactions of copper(I) halides with 2-(diphenylphosphano)benzaldehyde (PCHO) in 1:2 molar ratio afforded mononuclear complexes of the type [CuX(PCHO)(2)], whereas treatment of these compounds with equimolar amounts of pyridine-2-thione or pyrimidine-2-thione gave rise to the formation of mixed-ligand dimers of the formula [CuX(PCHO)(thione)](2). The molecular structures of [CuCl(PCHO)(2)], [CuBr(PCHO)(2)] and [CuCl(PCHO)(pymtH)](2) have been established by single-crystal X-ray diffraction. The two homoleptic complexes feature a trigonal copper(l) centre with the phosphatic acting as a monodentate ligand via the P atom. In the structure of the dimeric mixed-ligand complex each of the two metal centres exhibit a distorted tetrahedral environment with the thione-S atoms acting in a doubly bridging mode. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.09.001