[Cu2(succinamate)2Cl2(1,10-phenanthroline)2] | 1218772-93-0

• 英文名称: [Cu2(succinamate)2Cl2(1,10-phenanthroline)2]
• CAS: 1218772-93-0
• 化学式: C₃₂H₂₈Cl₂Cu₂N₆O₆
• 分子量: 790.609
• InChiKey: ZJMVCZWYALUYSB-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 丁酰胺酸 、 copper dichloride 在 LiOH*H₂O 作用下， 以 甲醇 为溶剂， 以50%的产率得到[Cu2(succinamate)2Cl2(1,10-phenanthroline)2]
  参考文献：
  名称：

  Synthetic, structural and spectroscopic studies of copper(II) complexes derived from the combination of the succinamate(−1) ligand with aromatic N,N′-chelates

  摘要：

  The use of succinamic acid (H(2)sucm)/N,N'-chelate (2,2'-bipyridine, bpy; 4,4'-dimethyl-2,2'-bipyridine, dmbpy; 1,10-phenanthroline, phen) 'ligand blends' in CuX2 center dot yH(2)O (X = NO3, y = 3; X = Cl, y = 0) chemistry has yielded the new complexes [Cu-2(Hsucm)(3)(bpy)(2)](NO3)center dot 0.5MeOH (1 center dot 0.5MeOH), [Cu-2(Hsucm)(OH)Cl(bpy)(2)](OH)center dot 3.6H(2)O (5 center dot 3.6H(2)O) and [Cu-2(Hsucm)(2)Cl-2(phen)(2)] (6). The succinamate(-1) ion behaves as a carboxylate ligand and exists in two different coordination modes in the structures of the above complexes, i.e., the common syn, syn mu(2)-kappa O:kappa O' in 1, 5 and 6, and the mu(2)-kappa O-2:kappa O' in 1. The primary amide group of Hsucm(-) remains uncoordinated and participates in intermolecular hydrogen bonding interactions leading to 1D, 2D and 3D networks. Characteristic IR bands of the complexes are discussed in terms of the known structures and the coordination modes of the Hsucm(-) ligands. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.11.007