| 1193721-36-6

• CAS: 1193721-36-6；175169-88-7
• 化学式: Br₁₆Re₄Te₈
• 分子量: 3044.09
• InChiKey: ICRBIQSOWFWBSY-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 、 二甲基苯基磷 以 二氯甲烷 为溶剂， 以74%的产率得到[Re4Te4(PMe2Ph)4Br8]*CH2Cl2
  参考文献：
  名称：

  Isomerism in tetrahedral rhenium cluster complexes [Re4Q4(PMe2Ph)4X8]·nCH2Cl2 (Q=Se, X=Br; Q=Te, X=Cl, Br)

  摘要：

  Three new tetrahedral rhenium cluster compounds [Re4Se4(PMe2Ph)(4)Br-8]center dot 1.5CH(2)Cl(2) (1), [Re4Te4(PMe2Ph)(4)Br-8]center dot CH2Cl2 (2), and [Re4Te4(PMe2Ph)(4)Cl-8]center dot CH2Cl2 (3) have been synthesized by the reaction of the corresponding precursor chalcohalide complexes [Re(4)Q(4)(TeX2)(4)X-8] (X = Br, Q = Se (for 1), Te (for 2); X=Cl, Q=Te (for 3)) with dimethylphenylphosphine in CH2Cl2. All compounds have been characterized by X-ray single-crystal diffraction and elemental analyses, IR and P-31 NMR spectroscopy. P-31 NMR spectroscopy indicates the formation of isomers in solution, confirmed by single-crystal X-ray analysis. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.07.003
• 作为产物：
  描述：

  碲化氢 、 rhenium bromide 、 溴 生成
  参考文献：
  名称：

  Isomerism in tetrahedral rhenium cluster complexes [Re4Q4(PMe2Ph)4X8]·nCH2Cl2 (Q=Se, X=Br; Q=Te, X=Cl, Br)

  摘要：

  Three new tetrahedral rhenium cluster compounds [Re4Se4(PMe2Ph)(4)Br-8]center dot 1.5CH(2)Cl(2) (1), [Re4Te4(PMe2Ph)(4)Br-8]center dot CH2Cl2 (2), and [Re4Te4(PMe2Ph)(4)Cl-8]center dot CH2Cl2 (3) have been synthesized by the reaction of the corresponding precursor chalcohalide complexes [Re(4)Q(4)(TeX2)(4)X-8] (X = Br, Q = Se (for 1), Te (for 2); X=Cl, Q=Te (for 3)) with dimethylphenylphosphine in CH2Cl2. All compounds have been characterized by X-ray single-crystal diffraction and elemental analyses, IR and P-31 NMR spectroscopy. P-31 NMR spectroscopy indicates the formation of isomers in solution, confirmed by single-crystal X-ray analysis. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.07.003