(N-[3-(2-aminoethylamino)propyl]salicylideneaminato-O,N,N',N'')bromozinc(II) | 164034-28-0

• 英文名称: (N-[3-(2-aminoethylamino)propyl]salicylideneaminato-O,N,N',N'')bromozinc(II)
• CAS: 164034-28-0
• 化学式: C₁₂H₁₈BrN₃OZn
• 分子量: 365.588
• InChiKey: HIBSMZILRGXYNQ-OVWKBUNZSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium hydroxide 、 zinc dibromide 、 [3-(2-aminoethylamino)propyl]salicylideneamine 以 甲醇 为溶剂， 以60%的产率得到(N-[3-(2-aminoethylamino)propyl]salicylideneaminato-O,N,N',N'')bromozinc(II)
  参考文献：
  名称：

  A New Schiff Base Complex: {N-[3-(2-Aminoethylamino)propyl]salicylideneaminato-O,N,N',N''}bromozinc(II)

  摘要：

  [Zn(satnen)Br], where satnen = H2N(CH2)(2)NH(CH2)3-N=CHC6H4O-, is the first example of a complex containing a tetradentate Schiff base derived from 1,6-diamino-3-azahexane. The Zn atom is bonded to five atoms (Br, O and three N atoms) and its coordination polyhedron can be described either as a distorted trigonal bipyramid (the Br atom being situated in the equatorial plane) or as a distorted tetragonal pyramid (with the Br atom at the apex). The Zn-Br bond is unusually long [2.4812(7) Angstrom]. The bonding distances within the phenyl ring vary between 1.34(2) and 1.42(1) Angstrom. The longer distances involve those C atoms which are connected either to O or to the C(H)=N-fragment. There are two intermolecular N-H ... X, X = Br, O, hydrogen bonds; the X = O bond is extremely weak.

  DOI：

  10.1107/s010827019401245x