Co(2-pyridineformamide N(4)-methylthiosemicarbazone)Cl2 | 252846-58-5

• 英文名称: Co(2-pyridineformamide N(4)-methylthiosemicarbazone)Cl2
• CAS: 252846-58-5
• 化学式: C₈H₁₁Cl₂CoN₅S
• 分子量: 339.174
• InChiKey: MLYBGWARBQDEJT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (Z)-2-(amino(pyridin-2-yl)methylene)-N-methylhydrazinecarbothioamide 、 cobalt(II) chloride 以 乙醇 为溶剂， 以65%的产率得到Co(2-pyridineformamide N(4)-methylthiosemicarbazone)Cl2
  参考文献：
  名称：

  Spectral and structural studies of iron(III), cobalt(II,III) and nickel(II) complexes of 2-pyridineformamide N(4)-methylthiosemicarbazone

  摘要：

  Reduction of 2-cyanopyridine by sodium in dry methanol in the presence of N(4)-methylthiosemicarbazide produces 2-pyridineformamide N(4)-methylthiosemicarbazone, HAm4M. Complexes with iron(III), cobalt(II,III) and nickel(II) have been prepared and characterized by molar conductivities, magnetic susceptibilities and spectroscopic techniques. In addition, the crystal structures of HAm4M, [Ni(Am4M)(OAc)], [Fe(Am4M)(2)]ClO4 and [Co(Am4M)(2)]ClO4 have been solved. Coordination is via the pyridyl nitrogen, imine nitrogen and thione or thiolato sulfur when coordinating as the neutral and anionic ligand, respectively. (C) 1999 Elsevier Science Ltd, All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00210-7