| 195205-82-4

• CAS: 195205-82-4
• 化学式: C₇H₁₃Cl₂NO₂PtS₂
• 分子量: 473.304
• InChiKey: YIDYWCARJCVUGC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 solid 为溶剂， 生成 chloroplatinum(1+);N-(2-ethoxy-2-oxoethyl)-N-methylcarbamodithioate
  参考文献：
  名称：

  Functionalized dithioester and dithiocarbamato complexes of platinum(II) halides

  摘要：

  Platinum dihalides react with the dithioester EtO2CCH2(CH3)NCS2Me (ESDTM) yielding the complexes Pt(ESDTM)X-2 and trans-Pt(ESDTM)(2)X-2 (X = Cl or Br). In the 1:2 adducts the ligand acts as monodentate through the thiocarbonyl sulfur, whereas it is S,S chelated in the Pt(ESDTM)X-2 species. These complexes release easily methyl halide either in solid or in solution to form species containing the related dithiocarbamato moiety (ESDT, EtO2CCH2(CH3)NCS2-). The first decomposition step in thermal degradation of the Pt(ESDTM)X-2 complexes involves evolution of one methyl halide molecule to form the related [Pt(ESDT)X](n) intermediate and leading finally to platinum metal. In the same conditions the trans-Pt(ESDTM)(2)X-2 complexes undergo demethylation of both ligand molecules, the Pt(ESDT)(2) intermediate being stable up to 250 degrees C. The dithioester adducts and the related degradation intermediates have been characterized by elemental analyses and IR and H-1 NMR spectroscopy. The complex behaviour in Various solvents has been described by proton NMR data. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00140-x
• 作为产物：
  描述：

  Ethyl 2-[methyl(methylsulfanylcarbothioyl)amino]acetate 、 platinum(II) chloride 以 苯 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Functionalized dithioester and dithiocarbamato complexes of platinum(II) halides

  摘要：

  Platinum dihalides react with the dithioester EtO2CCH2(CH3)NCS2Me (ESDTM) yielding the complexes Pt(ESDTM)X-2 and trans-Pt(ESDTM)(2)X-2 (X = Cl or Br). In the 1:2 adducts the ligand acts as monodentate through the thiocarbonyl sulfur, whereas it is S,S chelated in the Pt(ESDTM)X-2 species. These complexes release easily methyl halide either in solid or in solution to form species containing the related dithiocarbamato moiety (ESDT, EtO2CCH2(CH3)NCS2-). The first decomposition step in thermal degradation of the Pt(ESDTM)X-2 complexes involves evolution of one methyl halide molecule to form the related [Pt(ESDT)X](n) intermediate and leading finally to platinum metal. In the same conditions the trans-Pt(ESDTM)(2)X-2 complexes undergo demethylation of both ligand molecules, the Pt(ESDT)(2) intermediate being stable up to 250 degrees C. The dithioester adducts and the related degradation intermediates have been characterized by elemental analyses and IR and H-1 NMR spectroscopy. The complex behaviour in Various solvents has been described by proton NMR data. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00140-x