| 1450924-86-3

• CAS: 1450924-86-3
• 化学式: C₄₉H₅₅FeN₂O₂Sb
• 分子量: 881.585
• InChiKey: GXCPSHOWRBIIDT-WVABMSMOSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二茂铁甲酸 、 [o-C6H4(CHNC6H3iPr2-2,6)]Sb[o-C6H4CH2N(C6H3iPr2-2,6)] 以 正己烷 为溶剂， 反应 1.0h， 以82%的产率得到
  参考文献：
  名称：

  Opening of the azastibol heterocycle with various acids: Isolation of novel N,C-chelated organoantimony(III) compounds

  摘要：

  The reaction of N,C-intramolecularly coordinated organoantimony(III) compound L2SbCl (1) (where L is [2-(2',6'-i-Pr2C6H3)N=CHC6H4]) with one molar equivalent of the K-selectride (K[B(s-Bu)(3)H]) gave compound LSb{2-[CH2N(2',6'-i-Pr2C6H3)]C6H4} (2) containing five membered aza-stiba heterocycle. On the contrary, analogical reaction between the organobismuth(III) compound L2BiCl (3) and K-selectride gave only inseparable mixture of products. Reactions of 2 with selected acids HX resulted in the cleavage of the present Sb-N bond and formation of novel N, C-chelated compounds LSb(X){2-[CH2NH(2',6'-i-Pr2C6H3)]C6H4} (where X = Cl (4), CH3COO (5), CF3COO (6), CF3SO3 (7) or FcCOO (8); Fc = ferrocenyl). Compounds 4-8 were characterized by the help of elemental analysis, electrospray ionization (ESI) mass spectrometry, multinuclear NMR spectroscopy, IR spectroscopy and in the case of 5 by the single-crystal X-ray diffraction analysis. The molecular structures of compounds LSb(X){2-[CH2NH(2',6'-i-Pr2C6H3)]C6H4}center dot HX (where X = CF3COO (6a), CF3SO3 (7a)) were determined by the single-crystal X-ray diffraction analysis as well. Compounds 6a and 7a are most probably products of partial hydrolysis of compounds 6 and 7. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.06.023