[(MeOH)Al(N,N'-ethylenebis(3,5-di-tert-butylsalicylideneimine))((OMe)2PO(O))Al(N,N'-ethylenebis(3,5-di-tert-butylsalicylideneimine))((OMe)2PO(O))Al(N,N'-ethylenebis(3,5-di-tert-butylsalicylideneimine))]Br | 890084-06-7

• 英文名称: [(MeOH)Al(N,N'-ethylenebis(3,5-di-tert-butylsalicylideneimine))((OMe)2PO(O))Al(N,N'-ethylenebis(3,5-di-tert-butylsalicylideneimine))((OMe)2PO(O))Al(N,N'-ethylenebis(3,5-di-tert-butylsalicylideneimine))]Br
• CAS: 890084-06-7
• 化学式: Br*C₁₀₁H₁₅₄Al₃N₆O₁₅P₂
• 分子量: 1915.16
• InChiKey: QULRENNAIPRGEJ-FQOIRQAGSA-E

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  磷酸三甲酯 、 (N,N'-ethylenebis(3,5-di-tert-butylsalicylideneimine))AlBr 以 甲苯 为溶剂， 以54.3%的产率得到[(MeOH)Al(N,N'-ethylenebis(3,5-di-tert-butylsalicylideneimine))((OMe)2PO(O))Al(N,N'-ethylenebis(3,5-di-tert-butylsalicylideneimine))((OMe)2PO(O))Al(N,N'-ethylenebis(3,5-di-tert-butylsalicylideneimine))]Br
  参考文献：
  名称：

  Aluminum Phosphinate and Phosphates of Salen Ligands

  摘要：

  A new dealkylation reaction between organophosphate esters and Salen aluminum bromide compounds has been used to prepare three new aluminum salen compounds salen(Bu-t)AlOP(O)Ph-2 (1) (salen) N,N'-ethylenebis(3,5-di-tert-butylsalicylideneimine), [(MeOH)Alsalen(Bu-t){OMePO2(O)}Alsalen(Bu-t){OMePO2(O)}Alsalen(Bu-t)]Br (2), and [salpen(Bu-t)AlO](2)[(BuO)(2)PO](2) (3) (salpen) N,N'-propylenebis(3,5-di-tert-butylsalicylideneimine). Compounds 1 center dot MeOH, 2, and 3 were characterized by single-crystal X-ray diffraction. Compound 1 is the first example of a monomeric aluminum Schiff base phosphinate. Compound 2 is a cationic Salen aluminum phosphate, and compound 3 contains an aluminophosphate ring. This work is the first example of the intentional use of an aluminum-based dealkylation reaction to form new compounds.

  DOI：

  10.1021/ic052090k