[(η5-C5H4CH2Ph)Ru(CO)2(η1-S(dibenzothiophene)][BF4] | 936030-76-1

• 英文名称: [(η5-C5H4CH2Ph)Ru(CO)2(η1-S(dibenzothiophene)][BF4]
• 英文别名: [(η5-C5H4CH2Ph)Ru(CO)2(η1-(S)DBT)][BF4]
• CAS: 936030-76-1
• 化学式: BF₄*C₂₆H₁₉O₂RuS
• 分子量: 583.376
• InChiKey: ZUUWIUXYRVJFJD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  亚磷酸三苯酯 、 [(η5-C5H4CH2Ph)Ru(CO)2(η1-S(dibenzothiophene)][BF4] 以 硝基甲烷 为溶剂， 生成 [(η5-C5H4CH2Ph)Ru(CO)2(P(OPh)3)](1+)
  参考文献：
  名称：

  A new approach to the stabilization of dibenzothiophene (DBT) coordination to metals: Studies of (η5-C5H4CH2Ph)Ru(CO)2(η1(S)-DBT)+

  摘要：

  One approach to the removal of sulfur-containing compounds from transportation fuels involves the coordination of such compounds to transition metal complexes. We report the design and synthesis of a complex (eta(5)-C5H4CH2Ph)Ru(CO)(2)(eta(1)(S)-DBT)(+) that tests the concept that DBT binding through the sulfur can be augmented by pi-pi stacking interactions between a pendant phenyl group on the cyclopentadienyl ring and the DBT ligand. The crystal structure and kinetic binding studies of (eta(5)-C5H4CH2Ph)Ru(CO)(2)(DBT)(+) are reported and discussed. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.09.007
• 作为产物：
  描述：

  二苯并噻吩 、 benzylcyclopentadienyldicarbonylruthenium chloride 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 以47.7%的产率得到[(η5-C5H4CH2Ph)Ru(CO)2(η1-S(dibenzothiophene)][BF4]
  参考文献：
  名称：

  A new approach to the stabilization of dibenzothiophene (DBT) coordination to metals: Studies of (η5-C5H4CH2Ph)Ru(CO)2(η1(S)-DBT)+

  摘要：

  One approach to the removal of sulfur-containing compounds from transportation fuels involves the coordination of such compounds to transition metal complexes. We report the design and synthesis of a complex (eta(5)-C5H4CH2Ph)Ru(CO)(2)(eta(1)(S)-DBT)(+) that tests the concept that DBT binding through the sulfur can be augmented by pi-pi stacking interactions between a pendant phenyl group on the cyclopentadienyl ring and the DBT ligand. The crystal structure and kinetic binding studies of (eta(5)-C5H4CH2Ph)Ru(CO)(2)(DBT)(+) are reported and discussed. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.09.007