[Ru(p-cymene)(bipyridine)H] | 1056046-63-9

• 英文名称: [Ru(p-cymene)(bipyridine)H]
• 英文别名: [Ru(p-Cym)(bipy)H]
• CAS: 1056046-63-9
• 化学式: C₂₀H₂₃N₂Ru
• 分子量: 392.486
• InChiKey: VISLARDTVUHAMI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Ru(p-cymene)(bipyridine)H₂O](triflate)₂ 、 sodium tetrahydroborate 以 甲醇 为溶剂， 生成 [Ru(p-cymene)(bipyridine)H]
  参考文献：
  名称：

  Insights into the use of [Ru(p-Cym)(bipy)Cl]Cl as precatalyst for solvolytic dehydrogenation of ammonia-borane

  摘要：

  A detailed study on the use of [Ru(p-Cym)(bipy)Cl]Cl as precatalyst for the solvolytic dehydrogenation of ammonia-borane (AB) is presented. A new [Ru(p-Cym)(bipy)(NH3)](PF6) was synthesized and its dication identified as the dormant state of the catalyst after release of the hydrogen pressure from the reaction mixture. Exhaustive analysis of the activation procedure permitted us to establish an optimized experimental protocol to form the actual catalyst from either [Ru(p-Cym)(bipy) Cl]Cl or related precursors. Following this procedure, 2.62 equivalents of hydrogen per mol of ammonia-borane were released in 2.7 min at 49 degrees C. Kinetic experiments and a comparison on the use of different precatalysts are also presented. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2014.12.005