(η³-allyl)PdSbF₆ | 174659-56-4

• 英文名称: (η³-allyl)PdSbF₆
• 英文别名: (η3-allyl)palladium(II) hexafluoroantimonate
• CAS: 174659-56-4
• 化学式: C₃H₅Pd*F₆Sb
• 分子量: 383.233
• InChiKey: BQXSDQJJRABGRQ-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  silver hexafluoroantimonate 、 bis(η3-allyl-μ-chloropalladium(II)) 以 硝基甲烷 为溶剂， 生成 (η³-allyl)PdSbF₆
  参考文献：
  名称：

  High Tg sulfonated insertion polynorbornene ionomers prepared by catalytic insertion polymerization

  摘要：

  A simple method to synthesize high Tg sulfonated ionomers based on catalytic insertion polynorbornene is reported. Copolymers of norbornene and 5-methyl alcohol norbornene (endo:exo = 82:18) or 5-methyl bromide norbornene (endo:exo = 86:14) as well as terpolymers of norbornene, 5-methyl alcohol norbornene and 5-hexyl norbornene are prepared using a cationic Pd catalyst. These copolymers are then thioacetylated. Using hydrogen peroxide as oxidant, a sulfonated polynorbornene is obtained. Ionomers containing as much as 30 mol% SO3H and with Tgs above 200 degrees C are obtained in a four-step procedure of overall 40-75% yield. (C) 2016 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2016.01.047