[RuCl((R)-BINAPO)(1,10-phenanthroline)]PF6 | 476004-00-9

• 英文名称: [RuCl((R)-BINAPO)(1,10-phenanthroline)]PF6
• 英文别名: chlororuthenium(1+);[1-(2-diphenylphosphorylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;1,10-phenanthroline;hexafluorophosphate
• CAS: 476004-00-9
• 化学式: C₅₆H₄₀ClN₂OP₂Ru*F₆P
• 分子量: 1100.38
• InChiKey: BXTBMWSKLKPHET-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  15.91
• 重原子数：
  70
• 可旋转键数：
  7
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  42.8
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 氧气 、 Δ-cis-RuCl2((R)-BINAP)(1,10-phenanthroline) 以 甲醇 为溶剂， 以88%的产率得到[RuCl((R)-BINAPO)(1,10-phenanthroline)]PF6
  参考文献：
  名称：

  Formation of Ruthenium(II)−Bis(phosphine) Monoxide Complexes from the Bis(phosphine) Precursors:  BINAP-Monoxide (BINAPO) as a Six-Electron (P,O,η²- Naphthyl) Donor

  摘要：

  Aerobic oxidation of one P atom in cis-RuCl2(P-P)(L-2) complexes (P-P = (R)-BINAP (2,2'-bis(diphenylphosphino)-1,1'-binaphthyl) or dppb (1,4-bis(diphenylphosphino)butane), L-2 = bipy (2,2'-bipyridine) or phen (1,10-phenanthroline)) generates species such as [RuCl-(BINAPO)(L-2)]PF6 and cis-RuCl2(dppbO)(L-2) containing the corresponding bis(phosphine) monoxide ligands [BINAPO = 2-(diphenylphosphinoyl)-2'-(diphenylphosphino)-1,1'-(binaphthyl), and dppbO = 1-(diphenylphosphinoyl)-4-(diphenylphosphino)butane]. A novel coordination mode of BINAPO, involving the P-III atom, the O atom, and an eta(2)-naphthyl interaction proximate to the oxidized P atom, is identified by X-ray crystallography.

  DOI：

  10.1021/om0205344