dichloro[(1E,1'E)-1,1'-(pyridine-2,6-diyl)diethanone bis(O-methyloxime)-κ(3)N(1),N(2),N(6)]cobalt(II) | 935272-40-5

• 英文名称: dichloro[(1E,1'E)-1,1'-(pyridine-2,6-diyl)diethanone bis(O-methyloxime)-κ(3)N(1),N(2),N(6)]cobalt(II)
• CAS: 935272-40-5
• 化学式: C₁₁H₁₅Cl₂CoN₃O₂
• 分子量: 351.158
• InChiKey: SMYDTSSCNOPZCA-REQNFQRASA-L

反应信息

• 作为产物：
  描述：

  cobalt(II) chloride hexahydrate 、 1,1'-(pyridine-2,6-diyl)diethanone bis(O-methyloxime) 以 乙醇 为溶剂， 以68%的产率得到dichloro[(1E,1'E)-1,1'-(pyridine-2,6-diyl)diethanone bis(O-methyloxime)-κ(3)N(1),N(2),N(6)]cobalt(II)
  参考文献：
  名称：

  Dichloro[(1E,1′E)-1,1′-(pyridine-2,6-diyl)diethanone bis(O-methyloxime)-κ³N¹,N²,N⁶]cobalt(II)

  摘要：

  In the title compound, [CoCl2(C11H15N3O2)], the Co-II ion is five-coordinated in a strongly distorted square-pyramidal arrangement, with one of the two Cl atoms located in the apical position, and the other Cl atom and the three N-donor atoms of the tridentate methyloxime ligand located in the basal plane. The non-H atoms, except for the Cl atoms, lie on a mirror plane. The two equatorial Co-N-oxime distances are almost equal (mean 2.253 angstrom) and are substantially longer than the equatorial Co-N-pyridine bond [2.0390 (19) angstrom]. The structure is stabilized by intra- and intermolecular C-H center dot center dot center dot Cl contacts, which involve one of the methyl C atoms belonging to the methyloxime groups.

  DOI：

  10.1107/s0108270106026916