fac-Re(cis-bis(diphenylphosphino)ethylene)(CO)3Cl | 207796-30-3

• 英文名称: fac-Re(cis-bis(diphenylphosphino)ethylene)(CO)3Cl
• 英文别名: fac-Re(CO)3(cis-1,2-bis(diphenylphosphino)ethylene)Cl
• CAS: 207796-30-3
• 化学式: C₂₉H₂₂ClO₃P₂Re
• 分子量: 702.099
• InChiKey: WNWXBGUXBHGFFV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,10-菲罗啉 、 thallium(I) hexafluorophosphate 、 fac-Re(cis-bis(diphenylphosphino)ethylene)(CO)3Cl 以 邻二氯苯 为溶剂， 生成 cis-[Re(CO)2(cis-bis(diphenylphosphino)ethylene)(1,10-phenanthroline)]PF6
  参考文献：
  名称：

  一类新型的含顺式羰基配体的hen（I）发光聚吡啶配合物。

  摘要：

  A new class of long-lived luminescent complexes of the type cis-Re-I(CO)(2)(N-N)(P-P)(+) (where N-N is a chelate polypyridine ligand and P-P is a chelate phosphine) has been prepared. The new Re excited states are of extraordinary stability and exhibit redshifted spectral responses relative to the well-studied fac-Re(bpy)(CO)(3)L(+70) series (L is a variety of neutral and anionic ligands). Of primary interest are their extremely long lifetimes in CH2Cl2 solution, which could be a consequence of an energy gap law different from that of the tricarbonyl complexes.

  DOI：

  10.1021/ic971199s
• 作为产物：
  描述：

  五羰基氯铼(I) 、 顺-1,2-双(二苯基膦)乙烯 以 甲苯 为溶剂， 生成 fac-Re(cis-bis(diphenylphosphino)ethylene)(CO)3Cl
  参考文献：
  名称：

  一类新型的含顺式羰基配体的hen（I）发光聚吡啶配合物。

  摘要：

  A new class of long-lived luminescent complexes of the type cis-Re-I(CO)(2)(N-N)(P-P)(+) (where N-N is a chelate polypyridine ligand and P-P is a chelate phosphine) has been prepared. The new Re excited states are of extraordinary stability and exhibit redshifted spectral responses relative to the well-studied fac-Re(bpy)(CO)(3)L(+70) series (L is a variety of neutral and anionic ligands). Of primary interest are their extremely long lifetimes in CH2Cl2 solution, which could be a consequence of an energy gap law different from that of the tricarbonyl complexes.

  DOI：

  10.1021/ic971199s

文献信息

• Preparative Routes to Luminescent Mixed-Ligand Rhenium(I) Dicarbonyl Complexes
  作者：Joanna L. Smithback、Jeffrey B. Helms、Erick Schutte、Stephen M. Woessner、B. Patrick Sullivan

  DOI：10.1021/ic050707s

  日期：2006.3.1

  A series of mixed-ligand 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen) rhenium(I) dicarbonyl complexes that are emissive in fluid solution has been prepared, which includes a new class of the type cis-[Re(CO)2(P-P)(N-N)]+ (where P-P is a chelating diphosphine and N-N is a chelating polypyridine ligand). The four synthetic routes that have been developed rely on either reactive triflate displacement

  制备了一系列在流体溶液中发射的混合配体2,2'-联吡啶（bpy）和1,10-菲咯啉（phen）carbonyl（I）二羰基配合物，其中包括一类新的顺式[Re（CO）2（PP）（NN）] +（其中PP是螯合的二膦，NN是螯合的聚吡啶配体）。已经开发出的四种合成途径依赖于反应性的三氟甲磺酸酯置换或不稳定的氯配体的提取，然后利用P供体的强反式作用或直接利用P供体的反式作用。这些新配合物的光谱，光物理和电化学性质随着配位体中配体的净供体能力而系统地变化，如通过与Lever's E（L）参数的相关性所示。联吡啶配合物的寿命和量子产率涵盖25-1147 ns左右的范围。分别为0.002-0.11。