[Cu(I)(2,9-dimethyl-1,10-phenanthroline)(1,2-bis(diphenylphosphino)ethane)][PF6] | 713496-85-6

• 英文名称: [Cu(I)(2,9-dimethyl-1,10-phenanthroline)(1,2-bis(diphenylphosphino)ethane)][PF6]
• 英文别名: [Cu(1,2-bis(diphenylphosphino)ethane)(2,9-dimethyl-1,10-phenanthroline)]PF6；[Cu(1,2-bis(diphenylphosphino)ethane)(dimethylphenanthroline)](PF6)；[Cu(bis(diphenylphosphino)ethane)(2,9-dimethyl-1,10-phenanthroline)]PF6
• CAS: 713496-85-6
• 化学式: C₄₀H₃₆CuN₂P₂*F₆P
• 分子量: 815.197
• InChiKey: ZIKPRUQOCCAUEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,2-双(二苯基膦)乙烷 、 2,9-dimethyl-1,10-phenanthroline hydrate 、 tetrakis(actonitrile)copper(I) hexafluorophosphate 以 乙腈 为溶剂， 以70%的产率得到[Cu(I)(2,9-dimethyl-1,10-phenanthroline)(1,2-bis(diphenylphosphino)ethane)][PF6]
  参考文献：
  名称：

  Vorontsov, Ivan I.; Graber, Tim; Kovalevsky, Andrey Yu., Journal of the American Chemical Society, 2009, vol. 131, p. 6566 - 6573

  摘要：

  DOI：

文献信息

• Structure and Luminescence of a Dinuclear Copper Complex Bridged by a Diphosphine Ligand
  作者：Taro Tsubomura、Naoki Takahashi、Ken Saito、Toshiaki Tsukuda

  DOI：10.1246/cl.2004.678

  日期：2004.6

  A new dinuclear copper(I) complex containing two 2,9-di-methylphcnanthroline ligands and a bridging diphosphine ligand has been prepared. The structure of the complex was characterized by X-ray crystallography. A considerable blue shift was observed for the solid-state photoluminescence and absorption spectra of the complex as compared with the mononuclear mixed-ligand complex.

  一种新的双核铜 (I) 配合物包含两个 2,9-di-methylphcnanthroline 配体和一个桥接二膦配体已被制备。配合物的结构通过 X 射线晶体学表征。与单核混合配体配合物相比，该配合物的固态光致发光和吸收光谱发生了相当大的蓝移。
• A series of luminescent Cu(i) mixed-ligand complexes containing 2,9-dimethyl-1,10-phenanthroline and simple diphosphine ligands
  作者：Ken Saito、Takashi Arai、Naoki Takahashi、Toshiaki Tsukuda、Taro Tsubomura

  DOI：10.1039/b608641a

  日期：——

  A series of Cu(I) mixed-ligand complexes containing dmp (2,9-dimethyl-1,10-phenanthroline) and one of simple diphosphine ligands (Ph2P(CH2)nPPh2) were prepared. Among the complexes, [Cu(dppp)(dmp)]PF6 (n = 3) and [Cu2(dppb)2(dmp)2](PF6)2 (n = 4) were characterized by X-ray structure analyses. The dppp complex has been characterized as a mononuclear complex, while [Cu2(dppb)2(dmp)2]2+ exists as a dinuclear complex in which two dppb ligands bridge between the two Cu(I) atoms. Although the distorted tetrahedral structures around the central metals of the two complexes are similar, the P–Cu–P angles are different between the two complexes. All of the series of complexes show photoluminescence in solution, and the intensity of the luminescence increases with n (n = 2–4). The non-radiative rate constants of the complexes decrease markedly with n although radiative rate constants of the complexes are similar.

  制备了一系列含有 dmp (2,9-二甲基-1,10-菲咯啉) 和一个简单二膦配体 (Ph2P(CH2)nPPh2) 的 Cu(I) 混合配体配合物。在配合物中，[Cu(dppp)(dmp)]PF6 (n = 3) 和 [Cu2(dppb)2(dmp)2](PF6)2 (n = 4) 通过 X 射线结构分析进行了表征。 dppp 配合物被表征为单核配合物，而 [Cu2(dppb)2(dmp)2]2+ 作为双核配合物存在，其中两个 dppb 配体在两个 Cu(I) 原子之间桥接。尽管两种配合物中心金属周围的扭曲四面体结构相似，但两种配合物的 P-Cu-P 角不同。所有系列的配合物在溶液中均表现出光致发光，并且发光强度随着n (n = 2–4) 的增加而增加。尽管配合物的辐射速率常数相似，但配合物的非辐射速率常数随着n的增加而显着降低。