| 142691-59-6

• CAS: 142691-59-6
• 化学式: C₅₄H₄₄I₂P₂W
• 分子量: 1192.55
• InChiKey: NDUIKJGKTDBCGM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(acetonitrile)bis(η2-diphenylacetylene)diiodotungsten 、 1,2-双(二苯基膦)乙烷 以 二氯甲烷 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  The synthesis and reactions of the novel bis(diphenylacetylene) complex [WI2(NCMe)2(η2-PhC2Ph)2]

  摘要：

  The mono(acetonitrile) compound [WI2(CO)(NCMe)(eta-2-PhC2Ph)2] reacts in refluxing acetonitrile for 5 h in the presence of PhC2Ph to give the bis(acetonitrile) compound [WI2(NCMe)2(eta-2-PhC2Ph)2] (1) in high yield. Refluxing 1 in CHCl3 for 3 h affords the iodo-bridged dimer [W(mu-I)I(NCMe)(eta-2-PhC2Ph)2]2 (2). Compound 1 reacts with one equivalent and three equivalents of PPh3 to give [WI2(NCMe)(PPh3)(eta-2-PhC2Ph)2] (3) and [WI2(PPh3)3(eta-2-PhC2Ph)] (4), respectively. Equimolar quantities of 1 and Ph2P(CH2)nPPh2 (n = 1-3) react in CH2Cl2 at room temperature to give the acetonitrile displaced products [WI2{Ph2P(CH2)nPPh2}(eta-2-PhC2Ph)2] (5-7). Reaction of 1 with an equimolar amount of Na[S2CX] (X = NMe2 or NEt2) in CH2Cl2/MeOH 50:50 gives the iodo-bridged dimers [W(mu-I)(S2CX)(eta-2-PhC2Ph)2]2 (8 and 9). Two equivalents of Na[S2CX] (X = NMe2 or NEt2) react in CH2-Cl2/MeOH 50:50 at room temperature to afford the bis(dithiocarbamate) compounds [W(S2-CX)2(eta-2-PhC2Ph)2] (10 and 11). C-13 NMR spectroscopy suggests that the two diphenylacetylene ligands in [W(S2CX)2(eta-2-PhC2Ph)2] are donating a total of six electrons to the metal.

  DOI：

  10.1016/s0277-5387(00)84472-1