[(μ-SCH2N(C3H7)CH2S)Fe2(CO)5(PPh3)] | 933039-63-5

• 英文名称: [(μ-SCH2N(C3H7)CH2S)Fe2(CO)5(PPh3)]
• CAS: 933039-63-5
• 化学式: C₂₈H₂₆Fe₂NO₅PS₂
• 分子量: 663.318
• InChiKey: SIXHNQZGLQPGLE-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  [(μ-(SCH2)2N(CH2CH2CH3))Fe2(CO)6] 、 三苯基膦 在 Me₃NO*2H₂O 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 以97%的产率得到[(μ-SCH2N(C3H7)CH2S)Fe2(CO)5(PPh3)]
  参考文献：
  名称：

  Facile and highly efficient light-induced PR3/CO ligand exchange: A novel approach to the synthesis of [(μ-SCH2NnPrCH2S)Fe2(CO)4(PR3)2]

  摘要：

  A straightforward and efficient transformation of the Fe-S complex [(mu-SCH2N"PrCH2S)Fe-2(CO)(6)] to its double phosphine coordinated analogues [(mu-(SCH2NPrCH2S)-Pr-n)Fe-2(CO)(4)(PR3)(2)] (R = Ph, Me) is described. The single crystal structure of the PPh3-disubstituted Complex [(mu-(SCH2NPrCH2S)-Pr-n)Fe-2(CO)(4)(Ph3P)(2)] (3) showed that both of the phosphine ligands take an apical/apical instead of a basal/ basal or an apical/basal configuration. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.12.009