Ir(O2CPH)2(PMe3)3Cl | 1563173-75-0

• 英文名称: Ir(O2CPH)2(PMe3)3Cl
• 英文别名: Ir(O₂CPH)₂(tris-trimethylphosphine)Cl；Ir(O₂CPH)₂(PMe₃)₃Cl
• CAS: 1563173-75-0
• 化学式: C₂₃H₃₇ClIrO₄P₃
• 分子量: 698.139
• InChiKey: ARAHSRNDHFCNPD-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四氯化碳 、 HIr(O₂CPh)₂(tris-trimethylphosphine) 反应 72.0h， 生成 Ir(O2CPH)2(PMe3)3Cl 、 Ir(O2CPH)(PMe3)3Cl2
  参考文献：
  名称：

  Alkyne reactions with trimethylphosphine complexes of iridium: Lessons for the catalysis of vinyl ester formation and alkyne dimerization

  摘要：

  The combination of iridium with trimethylphosphine ligands yields very electron rich iridium compounds that are active for terminal alkyne dimerization chemistry as well as the addition of carboxylic acids to alkynes. The structures, catalytic and stoichiometric chemistry of some iridium tris-trimethly-phosphine compounds with benzoate ligands are detailed in this paper. The roles that these compounds may play in the catalytic cycles involved in the dimerization of terminal alkynes and the addition of benzoic acid to terminal alkynes are examined and possible mechanisms for these catalytic reactions are proposed. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.12.017