| 389064-00-0

• CAS: 389064-00-0
• 化学式: C₂₄H₂₀B*C₃₆H₃₉I₃P₃Ru
• 分子量: 1365.64
• InChiKey: FRNMGFYFYIQFPM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [(η5-C5Me5)ruthenium(Ph2PCH2CH2PPh2)(η1-tetrahedro-tetraphosphorus)]tetraphenylborate 、 碘 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of Exceptionally Stable Iron and Rutheniumη1-tetrahedro-Tetraphosphorus Complexes: Evidence for a Strong Temperature Dependence of M−P4 π Back Donation

  摘要：

  At variance with white phosphorus, the most reactive allotrope of the element, which is unstable and ignites spontaneously in air, the new η1 -tetrahedro-tetraphosphorus complexes [Cp*M(PR3 )2 (η1 -P4 )]Y (M=Fe, Ru; Y=Cl, PF6 , BPh4 , BAr$\rm{^{\prime }_{4}}$; Cp*=C5 Me3 the structure of the [Cp*Fe(Ph2 PCH2 CH2 PPh2 )(η1 -P4 )]+ ion is depicted) exhibit a surprising and unprecedented thermal stability and an astonishing reluctance to react with oxygen and other oxidants.

  DOI：

  10.1002/1521-3773(20011015)40:20<3910::aid-anie3910>3.0.co;2-2