[AlMe3(Ph2P(2-Me-8-quinolyl)=NBu(t))] | 627877-10-5

• 英文名称: [AlMe3(Ph2P(2-Me-8-quinolyl)=NBu(t))]
• CAS: 627877-10-5
• 化学式: C₂₉H₃₆AlN₂P
• 分子量: 470.574
• InChiKey: KHJXENNKQPNCKQ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [AlMe3(Ph2P(2-Me-8-quinolyl)=NBu(t))] 以 甲苯 为溶剂， 以96%的产率得到[AlMe2(CH(8-quinolyl)(Ph2P=NBu(t)))]
  参考文献：
  名称：

  Reactions of Iminophosphorano(8-quinolyl)methane with AlMe₃:  Unexpected Formation of Aluminum Iminophosphorano(2-methyl-8-quinolyl)methandiide Complex

  摘要：

  Reaction of Ph2P(8-CH2C9H6N)=NBut (1) with 2 equiv of AlMe3 in toluene under reflux conditions afforded aluminum iminophosphorano)(2-methyl-8-quinolyl)methandiide complex (2). The reaction proceeded via the intermediates of a coordination complex, [(AlMe3){Ph2P-(8-CH2C9H6N) =NBut}] (3), and then an addition complex (4) of AlMe3 to the carbon-nitrogen double bond of the quinolyl ring of the neutral ligand. The coordination complex was converted to the singly deprotonated complex [(AlMe2){CH(8-C9H6N)(Ph2P=NBut)}] (5) at 60 degreesC, which further reacted with AlMe3 in toluene under reflux conditions to yield aluminum iminophosphorano(8-quinolyl)methandiide (6). The structures of complexes 2, 4, and 6 were proved by single-crystal X-ray diffraction techniques, and the five-coordinate complexes 3 and 5 were characterized by Al-27 NMR spectroscopy.

  DOI：

  10.1021/om034045v
• 作为产物：
  描述：

  Ph2P(8-CH2quinolyl)=NBu(t) 、 三甲基铝 以 正己烷 、 苯 为溶剂， 以82%的产率得到[AlMe3(Ph2P(2-Me-8-quinolyl)=NBu(t))]
  参考文献：
  名称：

  Reactions of Iminophosphorano(8-quinolyl)methane with AlMe₃:  Unexpected Formation of Aluminum Iminophosphorano(2-methyl-8-quinolyl)methandiide Complex

  摘要：

  Reaction of Ph2P(8-CH2C9H6N)=NBut (1) with 2 equiv of AlMe3 in toluene under reflux conditions afforded aluminum iminophosphorano)(2-methyl-8-quinolyl)methandiide complex (2). The reaction proceeded via the intermediates of a coordination complex, [(AlMe3){Ph2P-(8-CH2C9H6N) =NBut}] (3), and then an addition complex (4) of AlMe3 to the carbon-nitrogen double bond of the quinolyl ring of the neutral ligand. The coordination complex was converted to the singly deprotonated complex [(AlMe2){CH(8-C9H6N)(Ph2P=NBut)}] (5) at 60 degreesC, which further reacted with AlMe3 in toluene under reflux conditions to yield aluminum iminophosphorano(8-quinolyl)methandiide (6). The structures of complexes 2, 4, and 6 were proved by single-crystal X-ray diffraction techniques, and the five-coordinate complexes 3 and 5 were characterized by Al-27 NMR spectroscopy.

  DOI：

  10.1021/om034045v