1-Isopropyl-4-methylbenzene (cyclohexa-1, 3-diene) Ru (0) | 500591-28-6

• 英文名称: 1-Isopropyl-4-methylbenzene (cyclohexa-1, 3-diene) Ru (0)
• 英文别名: IMBCHDRu (0)；Ru(p-cymene)(1,3-cyclohexadiene)；(η6-cymene)(η4-1,3-cyclohexadiene)ruthenium(0)；(η6-p-cymene)(1,3-cyclohexadiene)ruthenium(0)
• CAS: 500591-28-6
• 化学式: C₁₆H₂₂Ru
• 分子量: 315.421
• InChiKey: FOYJIIZDHOJDSZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1-Isopropyl-4-methylbenzene (cyclohexa-1, 3-diene) Ru (0) 、 dichloromethylphenylsulphide 、 三环己基膦 以 苯 为溶剂， 反应 12.0h， 以68%的产率得到双(三环己基磷)[(苯基硫)亚甲基]钌(II)二氯
  参考文献：
  名称：

  PROCESS FOR SYNTHESIS OF ORGANOMETALLIC COMPOUNDS

  摘要：

  公开号：

  EP1431302B1

文献信息

• Convenient Route to Fischer-Type Carbene Ruthenium Complexes:  Highly Selective Catalysts for Ring Opening/Cross-Metathesis of Norbornene Derivatives
  作者：Hiroyuki Katayama、Masato Nagao、Fumiyuki Ozawa

  DOI：10.1021/om020772z

  日期：2003.2.1

  The Fischer-type ruthenium carbene complexes RuCl2=C(H)ER}(PCy3)(2) (ER = SPh (1a), SC6H4Me-p (1b), SC6H4Cl-p (1c), SC6H4OMe-p (1d), SePh (1e)) have been prepared by the reactions of Ru(p-cymene)(cod), PCy3, and the corresponding dichloromethyl chalcogenides (Cl2CHER) in 47-80% yields. The starting Ru(p-cymene)(cod) is readily synthesized in high yield from [RuCl2(p-cymene)](2). The X-ray structures of 1b and 1e are reported. Complexes la and le serve as highly selective catalysts for ring opening/cross-metathesis of norbornene derivatives with vinyl chalcogenides.
• ZERO-VALENCE TRANSITION METAL COMPLEX AND METHOD OF SYNTHESIZING ORGANOMETALLIC COMPOUND FROM THE SAME AS STARTING MATERIAL
  申请人：SEKISUI CHEMICAL CO., LTD.

  公开号：EP1604964B1

  公开（公告）日：2009-06-10