(trichlorogermyl)methyl N-cyclohexylcarbamate | 824430-79-7

• 英文名称: (trichlorogermyl)methyl N-cyclohexylcarbamate
• CAS: 824430-79-7
• 化学式: C₈H₁₄Cl₃GeNO₂
• 分子量: 335.154
• InChiKey: VVHZFFZNYCODDS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  poly-1-vinyl-2-pyrrolidone 、 (trichlorogermyl)methanol 在 Et₃N 、 triethanolamine 作用下， 以 乙醚 为溶剂， 以46.9%的产率得到(trichlorogermyl)methyl N-cyclohexylcarbamate
  参考文献：
  名称：

  The structural peculiarities and chemical bonding in three organogermanes Cl3GeCH2OC(O)R with rigid coordination centre

  摘要：

  The molecular and crystal structure of three organogermanes Cl3GeCH2OC(O)R (where R =-NHC6H11, -C10H15, and -NH2) has been determined by X-ray diffraction method in order to investigate geometrical regularities of these molecules. The nature of Ge-O bonding in these molecules was investigated by quantum chemistry method. It was shown that the influence of the nature of ligand, attached to carbon atom of the carbonyl group, on Ge center dot center dot center dot O interatomic distance is incidentally small in isolated molecule while in the crystal it is much more pronounced due to the crystal packing effect. The nature of Ge center dot center dot center dot O bonding corresponds to intermediate type of interatomic interaction in terms of "Atoms in molecules" theory. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2007.04.019