(O-2-hydroxyethyl phenylphosphinite)pentacarbonylmolybdenum | 913341-62-5

• 英文名称: (O-2-hydroxyethyl phenylphosphinite)pentacarbonylmolybdenum
• CAS: 913341-62-5
• 化学式: C₁₃H₁₁MoO₇P
• 分子量: 406.14
• InChiKey: AQOJAESPOGICEN-NDQZBAIWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (7-phosphanobornadiene)pentacarbonylmolyddenum 、 乙二醇 在 1-methylimidazole 作用下， 以 甲苯 为溶剂， 以49%的产率得到(O-2-hydroxyethyl phenylphosphinite)pentacarbonylmolybdenum
  参考文献：
  名称：

  Generating Phosphinidene−N-Methylimidazole Adducts under Mild Conditions

  摘要：

  The nucleophilic attack of N-methylimidazole at the bridge phosphorus of a 7-phosphanorbornadiene pentacarbonylmolybdenum complex induces the collapse of the bridge. According to DFT calculations, the resulting zwitterion displays a very long and weak P-Mo bond. The excess of N-methylimidazole thus appears to be able to displace the phosphinidene from its molybdenum complex. The final result is a phosphinidene-N-methylimidazole adduct whose structure has also been computed. When applied to the phenyl derivative at 40 C in toluene, this reaction effectively generates the [PhP] adduct, which decomposes to give essentially Ph4P4 and Ph5P5. At 80 degrees C, PhPH2 is also produced. In the presence of CCl4 the phosphinidene adduct inserts into the C-Cl bond to give PhP(Cl) CCl3.

  DOI：

  10.1021/om060460m