| 874197-36-1

• CAS: 874197-36-1
• 化学式: C₄₃H₆₇FeKN₄O₂
• 分子量: 766.976
• InChiKey: GOGZRBMLDOBDIT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 N,N-dimethylanilinium tetraphenylborate 以 not given 为溶剂， 生成 [2,6-di(propan-2-yl)phenyl]-[1-[6-[1-[2,6-di(propan-2-yl)phenyl]azanidylethenyl]pyridin-2-yl]ethenyl]azanide;iron(2+);N-methylmethanamine
  参考文献：
  名称：

  Bis(imino)pyridine Ligand Deprotonation Promoted by a Transient Iron Amide

  摘要：

  Addition of 2 equiv of LiNMe2 to the bis(imino)pyridine ferrous dichloride, ((PDI)-P-iPr)FeCl2 ((PDI)-P-iPr = (2,6-Pr-i(2)-C6H3N=CMe)(2)C5H3N), resulted in deprotonation of the chelate methyl groups, yielding the bis(enamide)pyridine iron dimethylamine adduct, ((iPr)PDEA)Fe-(NHMe2) ((iPr)PDEA = (2,6-Pr-i(2)-C6H3NC=CH2)(2)C5H3N). Performing a similar procedure with KN(SiMe3)(2) in THF solution afforded the corresponding bis(THF) adduct, ((iPr)PDEA)Fe(THF)(2). ((iPr)PDEA)Fe-(NHMe2) has also been prepared by addition of the free amine to the iron dialkyl complex, ((PDI)-P-iPr)Fe(CH2SiMe3)(2), implicating formation of a transient iron amide that is sufficiently basic to deprotonate the bis(imino)pyridine methyl groups. Deprotonation of the amine ligand in ((iPr)PDEA)Fe(NHMe2) has been accomplished by addition of amide bases to afford the ferrous amide-ate complexes, [((iPr)PDEA)Fe(mu-NMe2)M] (M = Li, K).

  DOI：

  10.1021/ic051839o
• 作为产物：
  描述：

  乙醚 、 [2,6-di(propan-2-yl)phenyl]-[1-[6-[1-[2,6-di(propan-2-yl)phenyl]azanidylethenyl]pyridin-2-yl]ethenyl]azanide;iron(2+);N-methylmethanamine 、 双(三甲基硅烷基)氨基钾 以 乙醚 为溶剂， 生成
  参考文献：
  名称：

  Bis(imino)pyridine Ligand Deprotonation Promoted by a Transient Iron Amide

  摘要：

  Addition of 2 equiv of LiNMe2 to the bis(imino)pyridine ferrous dichloride, ((PDI)-P-iPr)FeCl2 ((PDI)-P-iPr = (2,6-Pr-i(2)-C6H3N=CMe)(2)C5H3N), resulted in deprotonation of the chelate methyl groups, yielding the bis(enamide)pyridine iron dimethylamine adduct, ((iPr)PDEA)Fe-(NHMe2) ((iPr)PDEA = (2,6-Pr-i(2)-C6H3NC=CH2)(2)C5H3N). Performing a similar procedure with KN(SiMe3)(2) in THF solution afforded the corresponding bis(THF) adduct, ((iPr)PDEA)Fe(THF)(2). ((iPr)PDEA)Fe-(NHMe2) has also been prepared by addition of the free amine to the iron dialkyl complex, ((PDI)-P-iPr)Fe(CH2SiMe3)(2), implicating formation of a transient iron amide that is sufficiently basic to deprotonate the bis(imino)pyridine methyl groups. Deprotonation of the amine ligand in ((iPr)PDEA)Fe(NHMe2) has been accomplished by addition of amide bases to afford the ferrous amide-ate complexes, [((iPr)PDEA)Fe(mu-NMe2)M] (M = Li, K).

  DOI：

  10.1021/ic051839o