| 437768-64-4

• CAS: 437768-64-4
• 化学式: CF₃O₃S*C₃₃H₃₄ClNPRuS
• 分子量: 793.273
• InChiKey: FPKHMGPDCAHQCY-OFIHFMIUSA-L

反应信息

• 作为产物：
  描述：

  dichloro(p-cymene)ruthenium(II) dimer 、 silver trifluoromethanesulfonate 、 1-phenyl-2-(2-pyridyl)-5-(2-thienyl)phosphole 以 二氯甲烷 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  A bridging ligand featuring terminal 2-pyridylphosphole moieties: synthesis, optical properties and Ru(II)-complex

  摘要：

  2,2'-Di[2-(5-(2-pyridyl)phospholyl)lthiophene (2a) has been obtained in 63% yield via the Fagan-Nugent's route. Derivative 2a possesses an extended pi-conjugated system and behaves as a bis(P.N-chelate) towards cationic (p-cymene)RuCl fragments affording the air-stable complex 3a in 60% yield. A diastereoselective coordination was observed and the solid state structure of the model Ru-complex 2b featuring a related 2-(2-pyridyl)-5-(2-thienyl)phosphole ligand is presented. (C) 2002 Elsevier Science B,V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01123-8