| 954149-77-0

• CAS: 954149-77-0
• 化学式: BF₄*C₃₅H₃₄FeN₂P
• 分子量: 656.294
• InChiKey: IBADGLPARNFOGI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  在 镍 作用下， 以 乙腈 为溶剂， 以59%的产率得到
  参考文献：
  名称：

  New (1‐Phosphanylferrocen‐1′‐ and ‐2‐yl)methyl‐Linked Diaminocarbene Ligands: Synthesis and Rhodium(I) Complexes

  摘要：

  AbstractTwo ferrocenylmethanols, [1′‐(diphenylthiophosphanyl)ferrocen‐1‐yl]methanol (3) and [2‐(diphenylthiophosphanyl)ferrocen‐1‐yl]methanol (6), have been converted in one step into the 1,1′‐ and 1,2‐ferrocenediyl‐linked thiophosphane/N‐R‐imidazolium salts 4a,b and 7a,b (a: R = Me; b: R = 2,4,6‐Me3C6H2 or Mes). This straightforward method allows the linkage of an imidazolium group to a ferrocene unit with a nonsubstituted methylene bridge. After desulfurisation of the phosphane group, the ligands reacted with an RhI precursor, in the presence of tBuOK, to give cationic complexes 9a,b and 10a,b. All compounds were characterised by elemental analysis, NMR spectroscopy and mass spectrometry. The molecular structures of compounds 4a, 7a and 9a were determined by X‐ray crystallography. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

  DOI：

  10.1002/ejic.200601193