[[Ag(cis,cis-1,3,5-triaminocyclohexane)](tetrafluoroborate)].infin. | 758695-00-0

• 英文名称: [[Ag(cis,cis-1,3,5-triaminocyclohexane)](tetrafluoroborate)].infin.
• CAS: 758695-00-0
• 化学式: Ag*BF₄*C₆H₁₅N₃
• 分子量: 323.878
• InChiKey: GYTPIWFIGDTOMK-XHTDGWPASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cis,cis-1,3,5-triaminocyclohexane 、 silver tetrafluoroborate 以 甲醇 、 水 为溶剂， 以46%的产率得到[[Ag(cis,cis-1,3,5-triaminocyclohexane)](tetrafluoroborate)].infin.
  参考文献：
  名称：

  Facile synthesis and structures of infinite one-dimensional silver(I) coordination polymers

  摘要：

  The synthesis and characterization of the isolated, infinite tubular coordination polymers {[Ag(cis-tach)]ClO4}(infinity) (1), {[Ag(transtach)]ClO4}(infinity) (2) and {[Ag(cis-tach)]BF4}(infinity) (3) has been achieved with the isomers cis, cis-1,3,5-triaminocyclohexane and cis,trans-1,3,5-triaminocyclohexane. Each new material has been fully characterized by single crystal X-ray diffraction, NMR, IR and elemental analysis. Compounds 1-3 form definite channels by the trigonal planar coordination of silver(l) metal centres to rigid, aliphatic triamino ligands, forming 4(2) (.) 6 topological networks. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.06.002