trans-[tetraphenylphosphonium][IrCl4(acetonitrile)(syn-1-chloro-2-nitroso-1,2-dihydrodicyclopentadiene)] | 906734-98-3

• 英文名称: trans-[tetraphenylphosphonium][IrCl4(acetonitrile)(syn-1-chloro-2-nitroso-1,2-dihydrodicyclopentadiene)]
• CAS: 906734-98-3
• 化学式: C₁₂H₁₅Cl₅IrN₂O*C₂₄H₂₀P
• 分子量: 912.145
• InChiKey: FSGQTZSIMPDYEZ-XIZMLWQZSA-J

反应信息

• 作为产物：
  描述：

  potassium pentachloronitrosyl iridate(III) 、 二聚环戊二烯 、 四苯基氯化膦 、 乙腈 以 乙腈 为溶剂， 生成 trans-[tetraphenylphosphonium][IrCl4(acetonitrile)(syn-1-chloro-2-nitroso-1,2-dihydrodicyclopentadiene)]
  参考文献：
  名称：

  Formation of Coordinated C-Nitroso Compounds by Reaction of K[IrCl₅NO] with Alkenes

  摘要：

  Coordinated C-nitrosochloroalkanes were obtained by electrophilic addition of K[IrCl5NO] to cyclooctene or dicyclopentadiene; in the last case, the crystal structure of trans-[IrCl4(CH3CN)(syn-1-chloro-2-nitroso-1,2-dihydrodicyclopentadiene)] was determined by X-ray diffraction. Although the reaction between NOCl and alkenes is well-known, there are Very few examples of clean electrophilic addition of coordinated NO+ to alkenes.

  DOI：

  10.1021/om060141v